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Home My WebLink AboutHAZMAT APPL 10/3/2008HAZARDOUS MATERIAL MANAGEMENT PLAN ;;: APPLICATIOW ~ ~~~~ BUSINESS OWNER/OPERATOR IDENTIFICATION FORM `:- (HAZARDOUS .MATERIAL FACILITY INFORMATION) 3~: ~ B 8 R S F I D P/RB ~ A~ T BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 Page 1 of 2 Fax: 661-852-2171 5~~ f`! - 4 f'.: ~ S ' 1 ~ t- ~-~ i 5:~ t ~ - S -~ S N~'~~~ i,~ .~G 4~~, Y~~ 'i,di~T 4~'~Yf~~!i- 5E f ~~f t~ ( 4' ~ . A J' 1'. ~ F S. 1 ~'4 -. 1 Wylr ~1' Y ~f~4 4 y~.~, + , . . y~ ' ~ I FACILITY IDENTIFICATION, ~ ~ ~ ~ x ~ ~ x ~ ~ K Y ~F , , ~,3 ,k t ; p , ~, $ ~ , , ~M 'l~ 1{ ~-~~Y 4~} ~`~ ~(r~ +~~ ai ~4 h14 { . :} h ~I . tf l~} N~i} k K, . fal i y. 1~ V% li~f ~Y h~ 7 ~~:1 ~ h ~ S N- 9 r _~ ~' ~ ~ ~ ~ ~ ~ ~ ~ ~ ~. d ~yk ~r;r.; N dd ;l~( ~ ~.,.,:,, ~ 1'L~~.. u , tb~zii~ ~."~.~e.l w„~., ~~ ~ i~.. ..:'rF .~~. '' ~~'~.w.~_~.a. ~..:P~'~k~~, W ,'~, ~c s;ut . ,x,.., ,v Y .e r ),,:d~'r..z . ~,~x ~ ._x,~ .~.~x . ~ FACILITY ID # " st~'. ° rkM1 U ~ 1 YEAR BEGINNING 100 ~ YEAR ENDING 101 ~-- 1 r ~ ~ I ~ ~ a l a- ~~ kN, ~~ BUStNE55 NAME (Same as FACILITV NAME or DBA) 3 BUSINESS PHONE lpz ~-f /~ ~t~t~ ~- ~ ,vc +~ ~ ~ S~ ~ L ~5 t ~ ~ Z~ lo~ ~ - ~5 - o I ~ 3 S1TE ADDRE55 1~ 3~ o f5 Ca I ~~ n~ ~ c~ de-~ ~ cm g~FK.ER,S~IELA ~~ .,) loa 2IPCODE ios / ~~ ~330 ~~ DUNN & BRADSTREET # I 106 $IC CODE 307 COUN7Y ~ / ~ / 108 ~ ..~ ~ J 309 . OPERATOR PHONE OPERATOR NAME 110 $ qllw ~~ k~' F ~~'r ~ M~S'~l<~ ~\ k~# ~J ka }(YY4'.13~yk4 h,~ y~~~ .+w~ 'M1. r 5+ _~~~ T~ r~'~ f~~'r~. '~ 'y. T 4~ S~ 1 } h ~~F `~F "t~YS 0h 7~7 F kG 1~~~~'j+~ ,F. .,3..,.;: .:. 15 1'~ J "~N K~ ~~~~" ~~ t~A ~ Y ~~; ~ '4G ~ d'~ Y 4 ` / ~ ~~ /I 'J .: 4 ~r ~ t~' ~~ ytk { t~' $j-0 '~ J1 ~J` ~~ ' ~ ,~ { 1 1 : { Ni 1 ~ 1 ~{1 s 1 ~ir 6 L ~~ ~J ~ y . ,;,~, ~;,,v ,,,,,.. 4, ,~~ ,~~,~.%, ~ti ~ II. OWNER INFORMATION < !I~ " A: <;~t: ct~ ~ `t~i f ~A +fW?~~ ~ t~ ~~+ ~~ Y '~ 4 "' ~ ~` k~ ~ ~ ~ ~ ~ ~~ ~ ' ' t ~ ~~ . .~ a .~,,i."' .r ' ~. ;y t :,i) k u,l ~l ~.,k,~P Hw n..~jY4Fx y.~ ~~ V s Ry~:.~.t i~ s : f j v..:-~4 a hJM' N . .~'C, tr i.tlic7,:~ iz -,:aM t t-;:= ar .:.~,. ~S 4 <4t ,.~. S ~' : :n~'~i.r , a~~r, ~„;},.~,~~i,1;. ei.A~~ ,~,~~,s~ ,. ~;.~.,~~~'af d,~{~~A,tr-.,,bkx ~s..~.~.,:~ ,.~,3d,,a.,.;+;~7~ thwg.~,r~,}~.~, .k k a... ~:.~.a .?::,,..~~1., a~'+ .i. ~~.,s~„w ~.~.117 I ~~~, ~.fi1 , ~.a .. ., ~ ..,,.... ,..~... ~~., .,.. . „ ....r...~~ ...a.i, i .,a . ~ ~a~vl l~-o lznrr o v~2 ~~~ ~~R~o~~,~3 - 5f~ yy ~~~ OWNER MAILING ADDRESS 3 - ~f '~- S~ S-~ C~ s-~- ~~3 CITY ~~ I~^ ^ ~ l~' ~ 114 ~' \I \ STAiE ^~ 115 ~~ ZIP C~QE/ ~~ ~ 116 `/ ~ t ~.% {}~€~sM1"' F~';v st" ~, y .Ct, L ~a' _+i '"` e_ ~''~-.-, x ~1~~ `~ t" Y-'[~~' :i .'' .~ ~,t ~\ } `k . ~ s Y~~~ .yv,.}~ ~ }E xhr"Y- `T t Y =~; E f ~ j ~ ~, III ENNIRONMENTAL CONTACT '' ~ , 3 ' .~ _ ~ ' ~, s~;~:x.~ ., ~ i ~, .~~~~~".,#~,. r,~:~ , ~,~~.~~-~~-,x :~~ ;>, .,~. , . T~ ~,F ~ ~ , . ~ ~ ~ ~ ~ , ~ ~ , ~ _ ~~ ~ ~ • 117 CONTACT NA ~iV ~/i/L-Un/MP~ ~ /~5~v/~ CONTACT PHONE ~ ~ ~ ~ r1 118 /~JD _ 7 7- 7 CONTA~ AILING ADD 5 ~~ ~ / ~~ ~/v ~ 119 3 v '~ i cmnv /`'/ ~/l J uo l~ srn~~ iii nvc~U '2. 02 / iu y . ..,. ._.. . . ..., . ,.,. .. ~ t / 1 "_y. b 1 :. ~ , .~. .~1 t y.Y-. }~ k'~y .~.' ~ f ~1 .'~ ~ ~ _ . Y~ .. f 4 ~ J d b ~; p :~. +,hp~` ~ ~' .• ~n k ie ~"K ~ ~ } naa~, :"k. ~' i t, r r,~a~f~~~ ~t ~~~,Fj~+~~ f.,,;R~ y r,~rk+~,~kF,~ 4~,~IV .s~'EMERGENCY.,CONTACTSa~ >E~~,s~~~,~a,~„n.r+~ +r~~ >;.l t«#r~ s~ F~ 'E~~~~)~,~Kw;~~~~«},r~~z;r,~~ ~ i i } ~ S S A 3 ~5'1 L '~ ~ .IS ~ S ^' {~S r ~ l ' ' ' v ~t ~ ~ ~ } i ~'~ '~ 1 1 ~ 3 ~ ~ t ~ 4~ ,V~~ yN~ ~ .,. q4 il {; ~n . ~,i '".Wf ~S{ 1 g{ ! fr. 1~ ~ . ~ ( ~L 4 '~"~i i~ .::rri '1+ ~ :4 ~i ?) ~~F i {^ ~ ...4 ' ,: ;4P 4){ G~t~ k ~,::'~IlrF t 4N ~ S. a { ii:~. F a~Gk }.~."4' ', Y ~.,~, y d :t;. ~ • y~.i ~ yh ~ ~ .,t. `~h , ~., ..., ~ ,.. 1 ~,, P ~1, ~~$ v s# J ,. a ~' ~,+ry~ .,~Mr ,.h.,.~ . „~i ....~.,,. ~. y.r > f~ ~-~ ~y ~ i ~~ ~ 7 ~ s: v,+, k., ~' Y ~ ~ c ~ ~ ~ ~L ~ r `~5 ! y k ~ ~~ ~ E t , ,. , wr 5~ F ~ ,Y z . iw .i a v, a k, ~c i ~Sf~y, i t pV r fll~ .~i '~V i~".'~~'.~; t N 4~.~.~y~ i ~^t . ) 4 a~s~, ~s~.~iPRIM'I~RYM ~,~~.f.~ aa,~~,~ ~.,~,~,~.~~.~ ~~,~~. v..~. .,.~. ~~~:.~..~ur ~~.,~n,~,,k~,~SECON~DARY~:->.~ ,~~,~~x~~a,~,.~~M~~s~~~*~,~~~~~~ NAME "~ 123 ~'Gf v~ /~ C> 12N ~ ri c~ ~Z NAME 128 ~l~G? ~/I P Y e 1~ 7iTLE D~~ ~^ 124 ~~ T[TLE ^ ~ 129 9j BUSINESS PMONE 125 ~l /- y~- ~Oa-~2~ BUSINESS PHONE 130 ~~/- Zz2-~3 ( 24HOUR PHONE ~ I _ 9 9 3 ~~ y 126 ~~ 24HOUR PHONE // ~ _ ~ ~ ~ - ~ ~ ~ ~ 131 ~~ 0 CELLPHONE ~ 127 CELL PHONE 132 133 j 21 y t~ '~k' 4`N ~ ~`}1 ~~ y1 ~ ~ Mi ~.1 ~t~~ 1 4jj, ~~ Y~ilrv r~:~~i l~i ~~ .G~~.i :.~'!; d t.",t^~i !W!} ~~ .. 11A ~r k~f }73 f`.. l~ ~, i ~f f ;~ ~ yv.t { ~ ji A~ ~ ~ ~ ~ ~ 5 t ~ ~ ~ 1~ ~'~ 1>~y t ~(,: ~ y~~ L µY ~re ~" ~ £ ~ t L. ~Y 4 ~ h}'f`.~~, yr Y 1 Y..i~~ .IN~~( N M~.41~'~, I i~1 u~1. y 4.~~'" 1 l}Rr~~M `4'Vk ~'}..~' fN fr rd M ~ ~ ~ Ft,~, N ,CERTIFICATION.zt ~ ,, z. ~f ~~ «,~ Ft ,~ ~s ~z r ~ ~ ~~ ~F ;f H ~4r fi~ ~~ ~~,~~I ~ ~ r ~ ~ ~~ ff n r-~ x+ ~ ~ ~r ~, ~ < "~ , ~ a , ; , ; ; ., . , , ~. r~:;~N. 1. .;~~uRr.3.,. ~'.~~:~.C^r .rr;.v,...k~:.s!v....... .v,~...r.tlS~i„{!'~vi.~l`.. r,~ ~'4.`i~ i$~uL..,swiuJ~'i,.a,.a'~~.:.~.,rk.~ .~ .~,..;i. ~;.:~'.,4~'N'~,.,:'hM~k,.'~~i~J.,.~.k'~;~L.N.1, ~rr.n,. }..},a~..~~' +~ "~ `~, 1 ~i~:ti c+7r~.,~"~! .1 ~rh , .~ Certification: Based on my inquiry of those individuals responsible for obtaining the information, I certify under penalty of law that I have personally examined and am familia the information submitted in this inventory and believe the information is true, accurate, and complete. SI6k URE F DOCU AENT PREP E,^, /„/ ,~ n 136 ~ ~ ~34 ~'0`,TE NAME 0 CUMENT PREPARER P T) . 135 - .~ v y~f ~.~C./ ~ _ `~ / V Q ~ ~ ~ri i N~NER/OPERATOR( I &~ ^ _ 137 ~vv \ : ~~ TITLE OF MENT PREPARER .~~ 138 FD2142 (Rev 01/08) HAZARDOUS MATERIAL FACILITY INFORMATION BUSINESS OWNER/OPERATOR IDENTIFICATION Page 2 of 2 Please submit the Business Activities page, the Hazardous Material Facility Information (HMMP) Business Owner/ Operator ldentification Form, and Hazardous Material Inventory Chemical Description Form for all hazardous material inventory submissions. For the inventory to be considered, please complete this page; it must be signed by the appropriate individual. NOTE: The numbering of the instructions follows the data element numbers that are on the.Business Owner/Operator Form page. These data element numbers are used for electronic submission and are the same as the numbering used in 27 CCR, Appendix C, Business Section of the Unified Program Data Dictionary. Please number all pages of your submittal. This helps our CUPA or AA identify whether the submittal is complete and if any pages are separated. 1 FACILITY I.D. NUMBER - This number is assigned by the CUPA or AA. This is the unique number which identifies your facility. 3 BUSINESS NAME - Enter the full legal name of the business. 100 BEGINNING DATE - Enter the beginning year and date of the report. 101 ENDING DATE - Enter the ending year and date of the report. 102 BUSINESS PHONE - Enter the phone number, area code first, and any extension. 103 BUSINESS SITE ADDRESS - Enter the street address where the facility is located. No post office box numbers are allowed. This information must provide a means to geographically locate the facility. 104 CITY - Enter the city or unincorporated area in which business site is located. 105 2IP CODE - Enter the zip code of business site. The extra 4-digit zip may also be added. 106 DUNN & BRADSTREET NUMBER - Enter the Dunn & Bradstreet number for the facility. The Dunn & Bradstreet number may be obtained by calling 610-882-7748 or by Internet. 107 SIC CODE - Enter the primary Standard Industrial Classification Code number for primary business activity. NOTE: If code is more than 4 digits, report only the first four. 108 COUNTY - Enter the county in which the business site is located. 109 BUSINESS OPERATOR NAME - Enter the name of the business operator. 110 BUSINESS OPERATOR PHONE - Enter business operator phone number, area code first, and any extension. 111 OWNER NAME - Enter name of business owner. 112 OWNER PHONE - Enter the business owner phone number, area code first, and any extension. 113 OWNER MAILING ADDRESS - Enter the owner mailing address. 114 OWNER CITY - Enter the city for owner mailing address. 115 OWNER STATE - Enter the 2 character state abbreviation for the owner mailing address. 116 OWNER ZIP CODE - Enter the zip code for the owner address; extra 4-digit zip may also be added. 117 ENVIRONMENTAL CONTACT NAME - Enter the name of the person who receives all environmental correspondence and will respond to enforcement activity. 118 CONTACT PHONE - Enter the phone number at which the environmental contact can be contacted, area code first, and any extension. 119 CONTACT MAILING ADDRESS - Enter the mailing address where all environmental contact correspondence should be sent. 120 CITY - Enter the name of the city for the environmental contact mailing address. 121 STATE - Enter the 2 character state abbreviation for the environmental contact mailing address. 122 ZIP CODE - Enter the zip code of the environmental contact mailing address; extra 4-digit zip may also be added. 123 PRIMARY EMERGENCY CONTACT NAME - Enter the name of a representative that can be contacted in case of an emergency, involving hazardous material, at the business site. The contact shall have FULL facility access, site familiarity, and authority to make decisions for the business regarding incident mitigation. 124 TITLE - Enter the title of the primary emergency contact. 125 BUSINESS PHONE - Enter the business number for the primary emergency contact, area code first, and any extensions. 126 24-HOUR PHONE - Enter a 24-hour phone number for the primary emergency contact. The 24-hour phone number must be one which is answered 24-hours a day. If it is not the contact home phone number, then the service answering the phone must be able to immediately contact the individual. 127 CELL NUMBER - Enter the cell number for the primary emergency contact. 128 SECONDARY EMERGENCY CONTACT NAME - Enter the name of a secondary representative that can be contacted in the event that the primary emergency contact is not available. The contact shall have FULL facility access, site familiarity, and authority to make decisions for the business regarding incident mitigation. 129 TITLE - Enter the title of the secondary emergency contact. 130 BUSINESS PHONE - Enter the business telephone number for the secondary emergency contact, area code first, and any extension. 131 24-HOUR PHONE - Enter a 24-hour phone number for the secondary emergency contact. The 24-hour phone number must be one which is answered 24-hours a day. If it is not the contact home phone number, then the service answering the phone must be able to immediately contact the individual. 132 CELL NUMBER - Enter the cell number for the secondary emergency contact. 133 ADDITIONAL LOCALLY-COLLECTED INFORMATION - This space may be used for CUPA or AA to collect any additional information necessary to meet the requirements of their individual programs. Contact your local agency for guidance. 134 DATE - Enter the date that the document was signed. 135 NAME OF DOCUMENT PREPARER (FULL PRINTED NAME) - Enter the full printed name of the person who prepared the inventory submittal information. 136 SIGNATURE OF DOCUMENT PREPARER (FULL SIGNATURE) - Enter the full signature of the person preparing the page. The signer certifies to a familiarity with the information submitted and that based on the signer inquiry of those individuals responsible for obtaining the information, all the information submitted is true, accurate, and complete. 137 SIGNATURE OF OWNER/OPERATOR/DESIGNATED REPRESENTATIVE - The Business Owner/Operator, or officially-designated representative of the Owner/Operator, shall sign and print in the space provided. This signature certifies that the signer is familiar with the signer belief that the submitted information is true, accurate, and complete. 138 TITLE OF DOCUMENT PREPARER - Enter the title of the person preparing the page. FD2142 (Rev 01/OS) HAZARDOUS MATERIAL MANAGEMENT PLAN ~; . . ,+: INSTRUCTIONS ~ ~ FOR SECTION DISCOVERY & NOTIFICATION ~ (FORMS) BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 • Fax: 661-852-2171 Page 1 of 2 The Business Owner/Operetor ldentification Form FD2089, Chemical Description Form FD2086, and other forms (underground storage tank information, hazardous waste treatment, etc.) may be submitted as the first section of the Hazardous Material Management Plan in order to avoid duplication of information for initial submissions. A. LEAK DETECTION AND MONITORING PROCEDURES: Describe the procedures and equipment used to detect any release or threatened release of a hazardous material from any storage container, tank, or vessel at your business. Please provide a written explanation that also includes the make and model number of any automated or electronic leak detection equipment in use at your facility. B. EMPLOYEE AND AGENCY NOTIFICATION: What agencies and/or corporate officials are notified in case of a hazardous material spill or emergency - what procedures are used to notify these parties? At a minimum, you must catl 911 and the Office of Emergency Services at 800-852-7550 to report any spills that are a threat to life, safety, or the environment, or for other non-emergency spill reporting, please call our office at 326-3979. C. ENVIRONMENTAL RESPONSE MANAGEMENT: Please describe who will be responsible for what activities (notifying authorities, clean-up companies, etc.), and what the chain-of-command is at your facility for making sure these activities are carried out. D. EMERGENCY MEDICAL PLAN: Summarize your plan for handling medical emergencies occurring at your business. List the local medical facility capable of handling an accident involving hazardous material used at your business. A. HAZARD ASSESSMENT AND PREVENTION MEASURES: Explain the procedures that you have developed and implemented to help prevent an incident from occurring. These steps could include, but are not limited to, storage methods, container types, segregation, safety equipment, and/or procedures used. B. RELEASE CONTAINMENT AND/OR MITIGATION: Explain the procedures that you have developed and implemented to assist in keeping a hazardous material incident at your business as small or confined as possible. C. CLEAN-UP AND RECOVERY PROCEDURES: Explain what clean up procedures will be implemented in case of a release at your business. This should address small spills as well as a major release of material once the material is contained. Flazardous Waste: Please provide the name of the hazardous waste company that regularly removes the waste from your business, and how often that waste is removed. Please keep all disposal receipts for the last three years available on site for inspection. H S R 9 P I 8 D P/R~ ~ ARTM T FD2169a (Rev O1/OS) Page 2 of 2 HAZARDOUS MATERIAL MANAGEMENT PLAN SECTION II.2 - RELEASE RESPONSE PLAN (CONT) UTILITY SHUT-OFFS List locations of shut-offs using compass points and known or obvious landmarks. If you have a lock box containing keys and maps of the facility for the Fire Department to use, please list its location also. PRIVATE FIRE PROTECTION/WATER AVAILABILITY A. Private Fire Protection: Describe on-site fire protection for your business or facility unit, including sprinklers, fire extinguishers, alarm systems, and private response teams. B. Water Availability (Fire Hydrant): Give the location of the closest water supply or fire hydrant to be used by the Fire Department in case of an emergency. SECTION III - TRAINING List the number of employees that are working in the area of the hazardous material, use, or storage. Include all employees who have any occasion to be in those areas. Give the location where Material Safety Data Sheets (MSDS) are kept on file. The MSDS must be readily available on site in a place where employees can access them. Give a brief summary of your Hazardous Material Training Program. Employees are required by State law to have a program which provides employees with initial and refresher training in the following areas: 1. Methods for safe handling of the hazardous material used by your business. 2. The Cal-OSHA Hazard Communication Standard. 3. Correct use of emergency response equipment and supplies available at your business. 4. The prevention, minimizing, and clean-up procedures you have developed for your business. 5. The emergency evacuation plans you have developed as well as your notification procedure and medical plan. 6. Procedure to coordinate with and assist the local emergency personnel that may respond to your business. 7. Who and how to call for immediate assistance in the event of an accident involving hazardous material. CERTIFICATION Please fill in your name, title, signature, and date on the signature line. IMPORTANT You must return this plan, inventory forms, and map within 30 days of receipt. If you have any questions please call us at 326-3464. Thank you for helping to keep our All America City cleaner and safer. CITY OF BAKERSFIELD BAKERSFIELD FIRE DEPARTMENT OFFICE OF PREVENTION SERVICES 1501 Truxtun Avenue, Bakersfield, CA 93301 FD2169a (Rev O1/OS) HAZARDOUS MATERIAL MANAGEMENT PLAN~ _. ,~X~ APPLICATION ~ FOR SECTION DISCOVERY & NOTIFICATION ~~'$ (FORMS) ~ BAKERSFIELD FIRE DEPARTMENT ~ Prevention Services 1501 Truxtun Avenue, 15i Floor H B R 9 P i a nBakersfield, CA 93301 P/Re Phone: 661-326-3979 • Fax: 661-852-2171 ~ aRr~r ~ r ~ Page i of 2 INSTRUCTIONS 1. To avoid further action, return this form within 30 days of receipt. 2. Type/print answers in ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. ' +' ~-.. ~ ^.. y r ~. ~.. ~ny ,','~*"~ o- ~-~~ ,~, 'y . u b .. ~" ~ wr ~~ . S+ 't~ ' ~ !s °a2 i: ;£~. '~ 'Se N,;~~ _ -r ., r ..~. x .~ d ^ f~ ;. e. . ~ ti : ~ ~ `' t ' ` t ~~ SECTION I• "FACILITY IDENTIFICATION x ' ' `' t"` ° ` ~~ ~: ,.. .. . _ ~... , ,, ,_ , , ~ . .s. .. , ~, .,~ .. LL . a _ . ~. . . ,~,. d. BUSINE55 NAME (FACILITY NAME or DBA) M/a T7-- T i~/~ 1~ Q~ S/ ~ ~~~ ~/7 2 C~ ADDRESS (for local use only) FACILITY ID # ~.~~,~ 1 .~- ~ ~ _.. ~ y ...~... 3< s r .<' ~ ~ .~~ . ~w, ~ -... ~ .i~ h r.~. t .fi. Y '~.-i ~. sl..':.S `b.r:. ,. .1. `, SECTION~~II~1; DISCOVERY AND;NOTIFICATIONS ~a ; ` ..'~``,~, ' ' , _ A. LEAK DEfECTION AND MONITORING PROCEDURES: • /~ ~U ~ ~ ~ t~v~ 2~.! ly ~-l Q~ir cc~ 2S v~S~oc.~.~~'~e e~,~~ ~ S °'~~ M~ P~ / ov r2 ~3 da~~ 7S ~ ~ B. EMPLOYEE AND AGENCY NOTIFICATION: ~~~v~ ~~~ J v/ `~ ~~~ ~w A J ~ ~~~ v/ nn S y ~G~ ~,~ ~ e~-~ v; l.C~ / / V V `~ / ~ / ~ ~ o / ~ ~~ NM~ AL RESPO~ v'EM~ i, ~/ M n ^ A ~ / ~ a~ ~~ ~ ~ ,L U /~ ~.( 'J'~' (/ , ~-C~ / ~~/ ~ ~ / J ~ (i ~ ~-1Ci ~/ ~?~Z t~TL A s's' / ~ ~ a v, a ~ ~-~ . D-,~ ~ v rL ~ D. EMERGENCY MEDICAL PLAN: p2 y ~ O U~S r'vU ~e SS I~/~/S ~GGL~~I (~C[ ~L %/li~' ~ / 87J0 - w~s~ t~v,•vc~ ~ ~~v~ svi ~ 3v~ ~a ~i~/Ls~j~l~lh~ ~°~~ ~~7- l~/ ~'133(1 .. . .x ~ e:~ ~ _ . . ,~_ ~ ..~ ..,., ~z: ~ :~~~~ .. ,~, .. :,.~ ~ ,. :.. ~'~ „ ;~~SECTION~'II,2, , RELEASE RESP.ONSE, PLAN ~ ` • ~ ` _ ., ~ , :, A. HAZARD ASSESMENT AND PREVENTION MEASURES: /~ ~~ ~j~,~ ~ ~ ~ ,~ ~ S ~~/fZ~ ~~ ~ ~ ~/ ~ ~ o~ ~/e ~~ A~ G( z~ U2 3 ~ ~ 7 ~ a c ~ y s~v CU v~ d v~ 6a ~~ ~-ril e 2~ ~~. ~ S a ~ ~ s~~ ~ ~z -~-P . B. RELEASE CONTAINMENT AND/OR MITIGATION: 'T /~L v es / ~/ / ~- J -e %2 a~/ ,~ (~ ~ J~2 ~ (l/~-~ ~ ~/ 5 ~ ~ ~ ~~,,- ~ . ~-r vs , ti ~ 2~,~ ,z~ ~~ ~ ~ r~ ~ ~ ~ ~~ G~ a ~~ ~ ~ s~ ~-~, ~ ~ ~ ,a rT ~ C. CLEAN-UP AND RECOVERY PROCEDURES: ~QS~v/2-~ ~ v~2v S-~=~~ ~~S Q,~r nc~ ~v~-'G' ~ y v~ ~ S ' ' ' Q L / lN u/ ~7 - 1i(/.~ ~/CGt~/~ ~S ~~G~, ~ -Jr °~ I~ ae~t~ . ~ ` `""~ ~ ~L~ ~i~u • FD2169 (Rev OS/08) Page 2 of 2 ~ ~'~ : a~ ~« ~~ ' S~ ~ °~ SECTION II.2` ~~RELEASE'RESPONSE PLAN (CONT)~ Y :%~~ ~ ~ $ ~~ ~~~,`~ , 4~ '` p~ ~ , p .t ( ~.i 3 P~ A~ ¢i~c.7. b'if. C.# .1'~a R.'1 ~~ ~.1~"~„5'CJ~.~ r$~ ~:dl~•'%~!P ~ A4 it (~~~1~.`n~ .%. ~ ~as•Y'a / iV 5~~ A. x 1~Q~i1 ~ F"~ .,'~ ,.e~ 4Z..A, ~xe ,h T.~t.r.l UTILITY SMUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY) ~ v ~ .~ ~ / G~t~. '~ n~ ~ ~dl/j L(/ -C C~ 0 t ( L ~ ~ ( ~( ~ i . il/ 1 / i L L~ . / N ~1~U ~/7- O ~ v ~ ~~ L: PRNATE FIRE PROTECTION/WATER AVAILABILITY: A. PRNATE FIRE PROTECTION: LJ ~I ~ ~~~ / N (~I ~~!/l~ ~ ~ ~ ~ ~~~ 0 ' '= ~ "'C~ ~ ~~/~/ -Cil / O ~7 / / B. WATER AVAILABILifV (FIRE HYDRAN~: ~ I._ ~~' C°Cc~ ~ ~G~i~~ ~. ~-~/ ~ _ ~ ~~,~.~._ ~r~.i ~ . ; :. . .,_ ~ , . ~. ~ ` 'SECTION' III TRAINING ~~ .. . . • , n, . , .. , ~ " h . c. , ~ ... nw.: ..7 ~„ ~Y'. , ~ : ,- - . ~a . :'4,_. L+ e . `t ~ ? '':'.( . . .,., ~ ,. .. . . . ,.. . ~.~. : . .. . .. r.,,. ., .. a*. . .., , . ~ . . . . x,.., o . ... . . . .... ., :c . - .. . . . . . . ~ ...... : . NUMBER OF EMPLOYEES: MATERIAL SAFETY DATA SHEETS ON FILE: YES ^ NO IF YES, LOCATION: ~ . D ~` BRIEF SUMMARY OF TRAINING VROGRAM: ~ G7L-~,~ . ~~ ~L~~. ~s ~ y , ~~J 3 U ~ c~ ~ ~ c -~r~-f~~ ~-cr 7 ~ ~ f, ~ ~r ~-~ M ,P ~ ~S ~ / , ; ~ ..;~ _.;:, -,;.. '.t... ~'~r, .'~ 4,.~~ ,, ry~ C'ERTI:FICA-TIO:N _ ; . . , .. _ . , .. . . : ~ .,: > , . ; .. . .:: . . , M.~ ,... ~ ...:. ,. , . ., , ~- Based o inquiry of those individuals responsible for obtaining the information, I certify under penalty of law that I have personally d' e ine a a familiar with the information submitted and believe the information is true, accurate, and complete. SIGNATU OWN R/OPERAT OR DESIGNATED REPRESENTATNE DATE a77 /0-3 ~ NA 0 (PRINT) ^ 478 TITLE OF SI NER 479 ..~ J~ ~V ~'- / FD2169 (Rev 01/08) HAZARDOUS MATERIAL MANAGEMENT PLAN ~ INSTRUCTIONS B~, B R S F I B p P/R! CHEMICAL DESCRIPTION FORM ! ART~ ~ f HAZARDOUS MATERIAL INVENTORY FORM ~ BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 • Fax: 661-852-2171 Page i of 3 Make as many copies of the chemical description form as necessary to report your entire inventory of hazardous material. Report every hazardous material handled in quantities equal to or exceeding 55 gallons of a liquid, 500 pounds of a solid, or 200 cubic feet of a gas. Report ~py amount of any hazardous waste being generated or handled on site. I. FACILITY INFORMATION: 1 FACILITY I.D. NUMBER - This number is assigned by the CUPA or AA. This is the unique number which identifies your facility. 3 BUSINESS NAME - Enter the full legal name of the business. II. CHEMICAL INFORMATION: Each of the instructions below corresponds to the entry field with the same number on the chemical description form. 200 ADD/DELETE/REVISE - Indicate if the material is being added to the inventory, deleted from the inventory, or if the information previously submitted is being revised. NOTE: You may choose to leave this blank if you resubmit your entire inventory annually. 201 CHEMICAL LOCATION - Enter the building or outside/adjacent area where the hazardous material is handied. A chemical that is stored at the same pressure and tempereture, in multiple locations within a building, can be reported on a single page. NOTE: This information is not subjed to public disclosure pursuant to HSC §25506. 202 CFIEMICAL LOCATION CONFIDENTIAL - EPCRA - All businesses which are subject to the Emergency Planning and Community Right to Know Act (EPCRA) must check yes to keep chemical location information confidential. If the business does not wish to keep chemical Iocation information confidential check no. 203 MAP NUMBER - If a map is included, enter the number of the map on which the location of the hazardous material is shown. 204 GRiD NUMBER - If grid coordinates are used, enter the grid coordinates of the map that correspond to the location of the hazardous material. If applicable, multiple grid coordinates can be listed. 205 CHEMICAL NAME - Enter the proper chemical name associated with the Chemical Abstract Service (CAS) number of the hazardous material. This should be the International Union of Pure and Applied Chemistry (IUPAC) name found on the Material Safety Data Sheet (MSDS). NOTE: If the chemical is a mixture or a hazardous waste, do not complete this field; complete the "common name" field instead. 206 TRADE SECRET - Check "Y" for yes if the information in this section is declared a trade secret, or "N" for no if it is not. State requirement: If yes, and business is not subject to EPCRA, disclosure of the designated trade secret information is bound by Health and Safety Code, Section 25511. Federal Requirement: If yes, and business is subject to EPCRA, disclosure of the designated Trade Secret information is bound by Title 40 Code of Federal Regulations (CFR) and the business must submit a Substantiation to Accompany Claims of Trade Secrecy form (40 CFR 350.27) to USEPA. 207 COMMON NAME - Enter the common name or trade name of the hazardous material or mixture containing a hazardous material. 208 EHS - Check "Y" for yes if the hazardous material is an Extremely Hazardous Substance (EHS), as defined in 40 CFR, Part 355, Appendix A. If the material is a mixture containing an EHS, leave this section blank and complete the section on hazardous 209 CAS - Enter the Chemical Abstract Service (CAS) number for the hazardous material. For mixtures, enter the CAS number of the mixture if it has been assigned a number distinct from its components. If the mixture has no CAS number, leave this column blank and report the CAS numbers of the individual hazardous components in the section below. 210 FIRE CODE HAZARD CLASES (leave blank) 211 HAZARDOUS MATERIAL TYPE - Check the one box that best describes the type of hazardous material: pure, mixture, or waste. If waste material, check only that box. If mixture or waste, complete hazardous components section. 212 RADIOACTIVE - Check "Y" for yes if the hazardous material is radioactive or "N" for no if it is not. 213 CURIES - If the hazardous material is radioactive, use this area to report the activity in curies. You may use up to nine digits with a floating decimal point to report activity in curies. 214 PHYSICAL STATE - Check the one box that best describes the state in which the hazardous material is handled: solid, liquid, or gas. 215 LARGEST CONTAINER - Enter the total capacity of the largest container in which the material is stored. 216 FEDERAL HAZARD CATEGORIES - Check all the physical and health hazards associated with the hazardous material: PHYSICAL HA2ARDS: 1 Fire: Flammable liquids and solids, combustible liquids, pyrophorics, oxidizers 2 Reactive: Unstable reactive, organic peroxides, water reactive, radioactive 3 Pressure Release: Explosives, compressed gases, blastin9 agents HEALTH HAZARDS: 4 Acute Health (Immediate): Highly toxic, toxic, irritants, sensitizers, corrosives, other hazardous chemicals with an adverse effect with short-term exposure. 5 Chronic Health (Delayed): Carcinogens, other hazardous chemicals with an adverse effect with long-term exposu re. 217 ANNUAL WASTE AMOUNT - If the hazardous material being inventoried is a waste, provide an estimate of the annual amount handled. 218 MAXIMUM DAILY AMOUNT - Enter the maximum amount of each hazardous material or mixture containing a hazardous material, which is handled in a building or adjacent/outside area at any one time over the course of the year. This amount must contain at a minimum last year's inventory of the material reported on this page, with the reflection of additions, deletions, or revisions projected for the current year. This amount should be consistent with the units reported in Box 221. 219 AVERAGE DAILY AMOUNT - Calculate the average daily amount of the hazardous material or mixture containing a hazardous material in each building or adjacent/outside area. Calculations shall be based on the previous year's inventory of material reported on this page. Total all daily amounts and divide by the number of days the chemical will be on site. If this is a material that has not previously been present at this location, the amount shall be the average daily amount you project to be on hand during the course of the year. This amount should be consistent with the units reported in Box 221 and should not exceed that of maximum daily amount. 220 STATE WASTE CODE - If the hazardous material is a waste, enter the appropriate California 3-digit hazardous waste code as listed on the back of the Uniform Hazardous Waste Manifest. A list of common State Waste Codes is included on page 3 of these instructions. FD2144a (Rev 01/08) HA2ARDOUS MATERIAL MANAGEMENT PLAN INSTRUCTIONS FOR HAZARDOUS MATERIAL INVENTORY CHEMICAL DESCRIPTION FORM Page 2 of 3 221 UNITS - Check the unit of ineasure that is most appropriate for the material being reported on this page: gallons, pounds, cubic feet or tons. NOTE: If the material is a Federally-defined Extremely Hazardous Substance (EHS), all amounts must be reported in pounds. If material is a mixture containing an EHS, report the units that the material is stored in (gallons, pounds, cubic feet, or tons). 222 DAYS ON SITE - List the total number of days during the year that the material is on site. 223 STORAGE CONTAINER - Check all boxes that describe the type of storage containers in which the hazardous material is stored. NOTE: If appropriate, you may choose more than one. 224 STORAGE PRESSURE - Check the one box that best describes the pressure at which the hazardous material is stored. 225 STORAGE TEMPERATURE - Check the one box that best describes the temperature at which the hazardous material is stored. 226 HAZARDOUS COMPONENT i-5 (% BY WEIGHT) - If a range of percentages is available, report the highest percentage in that range. 230 HAZARDOUS COMPONENT i-5 (% BY WEIGHT) - If a range of percentages is available, report the highest percentage in that range. 234 HAZARDOUS COMPONENT 1-5 (% BY WEIGHT) - If a range of percentages is available, report the highest percentage in that range. 238 HAZARDOUS COMPONENT 1-5 (% BY WEIGHT) - If a range of percentages is available, report the highest percentage in that range. 242 HAZARDOUS COMPONENT 1-5 (% BY WEIGHT) - If a range of percentages is available, report the highest percentage in that range. 227 HAZARDOUG COMPONENT 1-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chemical composition should be listed. 231 HAZARDOUG COMPONENT 1-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chemical composition should be listed. 235 HAZARDOUG COMPONENT 1-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chemical composition should be listed. 239 HAZARDOUG COMPONENT 1-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chemical composition should be listed. 243 HAZARDOUG COMPONENT i-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chemical composition should be listed. 228 HAZARDOUS COMPONENT 1-5 EHS - Check "Y" for yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or "N" for no if it is not. 232 HAZARDOUS COMPONENT 1-5 EHS - Check "Y" for yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or "N" for no if it is not. 236 HAZARDOUS COMPONENT 1-5 EHS - Check "Y" for yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or °N" for no if it is not. 240 HA2ARDOUS COMPONENT 1-5 EHS - Check "Y" for yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or "N" for no if it is not. 244 HA2ARDOUS COMPONENT 1-5 EHS - Check "Y" for yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or "N" for no if it is not. 229 HA2ARDOUS COMPONENT i-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. 233 HA2ARDOUS COMPONENT 1-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. 237 HAZARDOUS COMPONENT 1-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. 241 HAZARDOUS COMPONENT 1-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. 245 HA2ARDOUS COMPONENT 1-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. III. SIGNATURE 246 SIGNATURE - Print name, title, sign, and date each chemical description form. FD2144a (Rev O1/08) Page 3 of 3 CALIFORNIA WASTE CODES ~,~ Descri t~~ ion Inorganics 111 Acid solution 2< pH < 7 with metals (antimony, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, lead, mercury, molybdenum, nickel, selenium, silver, thallium, vanadium, and zinc) 112 Acid solution without metals 113 Unspecified acid solution 121 Alkaline solution pH >12.5 with metals (see 111) 122 Alkaline solution without metals 123 Unspecified alkaline solution 131 Aqueous solution (2 < pH < 12.5) containing reactive Anions. (azide, bromate, chlorate, cyanide, fluoride, hypochlorite, nitrite, perchlorate and sulfide anions) 132 Aqueous solution with metals (see 111) 133 Aqueous solution with total organic residues 100% or more 134 Aqueous solution with total organic residues < 10% 135 Unspecified aqueous solution 141 Off-spec, aged, or surplus inorganics 151 Asbestos containing waste 161 FCC Waste 162 Other spent catalyst 171 Metal sludge (see 111) 172 Metal dust and machining waste (see 111) 181 Other inorganic solid waste Code Descri tp ion Organics (cont) 261 PCB and material containing PCB 271 Organic monomer waste (includes unreacted resins) 272 Polymeric resin waste 281 Adhesives 291 Latex waste 311 Pharmaceutical waste 321 Sewage sludge 322 Biological waste other than sewage sludge 331 Off-spec, aged or surplus organics 341 Organic liquids (non-solvents) with halogens 343 Unspecified organic liquid mixture 351 Organic solids with halogens Sludge 411 Alum and gypsum sludge 421 Lime sludge 431 Phosphate sludge 441 Sulfur sludge 451 Degreasing sludge 461 Paint sludge 471 Paper sludge/pulp 481 Tetraethyl lead sludge 491 Unspecified sludge waste Organics 211 Halogenated solvents (methylene chloride, chloroform, TCE, TCA) 212 Oxygenated solvents (acetone, butanol, MEK) 213 Hydrocarbon solvents (Stoddard solvent, xylene) 214 Unspecified solvent mixture 221 Waste oil and mixed oil 222 Oil/water separation sludge 223 Unspecified oil - containing waste 231 Pesticide rinse water 232 Pesticide and other waste associated with pesticide production 241 Tank bottom waste 251 Still bottoms with halogenated organics 252 Other still bottom waste Miscellaneous 511 Empty pesticide containers 30 gal or more 512 Other empty container 30 gal or more 513 Empty containers less than 30 gal 521 Drilling mud 531 Chemical toilet waste 541 Photo chemical/photo processing waste 551 Laboratory waste chemicals 561 Detergent and soap 571 Fly ash, bottom ash, and retort ash 581 Gas scrubber waste 591 Bag house waste 611 Contaminated soil from site clean-ups 612 Household wastes FD2144a (Rev O1/08) , BAKERSFIELD FIRE DEPARTMENT . Prevention Services HAZARDOUS MATERIAL MANAGEMENT PLAN ~4~ H H R S A~ n 1501 Truxtun Avenue, 1~* Floor ~ p/RB Bakersfield, CA 93301 CHEMICAL DESCRIPTION FORM AR1~ t Phone: 661-326-3979 • Fax: 661-852-2171 HAZARDOUS MATERIAL INVENTORY ~~` ~ Page 1 of 2 ^ NEW ^ ADD ^ DELETE ^ REVISE zao /llnn fnrm .. ...~re.~ r ~.. k ~ ~,/t 1~ti . 4~ ~,~7~~i y ,'il 1~ ~ 1 l hy- {~'1~.-~:~' b ~ ,b}.;~.~'J ^4,}s~y~.:~~~. 6'?&9, r ( `7 ~ N~ (~ 1r,"}i' ry~ry~ b+6~ 1.'~~' C'~N~~L.:~ a l ..qr~{. ..:;. '. .4 ~'5.~~, ~' t~~ 5~' lC J ~ ~ 3 t ~ E ' ' R < ~ ~ ~ `~ ~~5 ~ iu~ ~4' 3 '~ tYr ~ 3 ~ ' ` r ' ~ ~ 4 ` x } k ~ A6 y 4 s t . f ~T. P~ f ~f5~ {$ p~- 4'~. . ~f P ~f } . '..+F *f i 4f .u l t~.C 4}' ~} tj ( M! C~, ~ l S . ('~' S t' . E~S.T SrN 4 '2 e., ~ ~ ~§ ~ ~ ~ ~~~~ I FACILITYtINFORMATION ~ ~ `w ~` ` ~ ~ ~ F ~~F~~ l ' i '~ i ' :l A -~ ~ ~ ° ~ ~ r ~ ~f ~ ~ x ~~ . ~4k y ,~ 'r We 1 4 hl S.~ F~.~ [ H } ? i S~x 1 1 4 k~ 4 ~ h~ Yr 4 l,:v ~ ~ ~ - ~ , o~, , ~ ,. . .~ >, . ~ ~., ~ ~ ' ~. . ~:. ~. ~ ..! ,. , .;,a~ t .~, , ;.~f „ l~.r "";' x ~J~x,^~.ti•d, „~l„~r ^iA., '~, '~y .'a '~ ~u, ~'i rii ~ ~~. , ~ .c.. ,. ~ .~ ~ ~. . + , , .a.. . , >f`~.. , t.d #$. 9,'7~~~ . ,. BUSINESS NAME (FACILIIY NAME or DBA) 3 CHEMICAL LOCATION 201 CHEMICAL LOCATION 202 CONFIDENTIAL (EPCRA) ^ Yes ^ No FACILIIY ID # ,`~~;,t ~~, 1 MAP #(aptianaq 203 GRID #(optional) 20a ~~~~ F~ ~;. -~wi''~ ~ ~ .~; w ~qt 1 b} ~; ~ '4 + fy ~F k '. kYTiy 2 9~ ~~£ ~~l .~ ~~ l~ A4 ~. ~ 4.1k:'.- f. }. a.~ t! .7 T 4''~^ 4 ,d+.Fr 'u } 65_'Y~~i ,~"'' F ~ ,~'va~ ~€ W } '"Y ` .$5 ~i' f µ3 ~~,C "M ^e~'AS~~li ~`7. y~ "s~ ~.,r'~ ~ ~ i . 4i h ° ~ ~~~a ° ~ ~ ~ v ~ « ° ~ I~ ~CHEMICAL INP ORMATIONs~ 4 4~~ w ~ ~ ~ ~ ~ `~ ~ " ~~ ~ ~ , ~ , .'~~ f .Y Y . ~' ) ~ i ~" ..nf~i . 1 ..5~. ~. ~ x6 , , cf. .~. ..~'Sb..,. ~ 1 L , f . .. ,. <. . , ... ~.,., .~ s.. , , .... . ..~,. ..._ ,,. . <.. ~,n...e, .~, .,~.,., ~,,,. CHEMICALNAME 205 206 TRADE SECRET ^ Yes ^ No If subjec[ [o EPCRA, reter to ins[ruc[lons COMMON NAME zp7 EHS* ^ Yes ^ No 208 CAS # 209 *If EHS is yes, all amounLS below must be in pounds. FIRE CODE HAZARD CLASSES (complete if requested by local flre chie~ 210 7YPE nl ZlZ CURIES 2i3 RqDIOACTIVE: ^ Yes ^ No ^ PURE ^ MIXTURE ^ WASTE LARGEST CONTAINER 235 PHYSICAL STATE ^ SOLID 0 LIQUID ^ Gns 21a 216 FED HAZARD CATEGORIES ^ FIRE ^ REACTIVE ^ PRESSURE RELEASE ^ ACUTE HEALTH ^ CHRONIC HEALTH (Check all that apply) ANNUAL WASTE Z17 MAXIMUM 218 AVERAGE 219 STATE WASTE 220 AMOUNT DAILY AMOUNT DAILY AMOUNT CODE ZZ1 DAYS ON SITE 222 ^ UNITS~ ^ GAL ^ CU Ff ~ LBS ^ TONS 'If EMS, amount mu5t be in Ibs. STORAGE CONTAINER: ZZ3 ^ ABOVEGROUND TANK ^ CAN ^ BOX ^ TANK WAGON ^ UNDERGROUND TANK ^ CARBOY ^ CYLINDER 0 RAILCAR ^ TANKINSIDE BUILDING ^ SILO ^ GLASS BOlTLE ^ OTHER ^ STEEL DRUM ^ FIBER DRUM ^ PLASTIC BOTTLE ^ TOTE BIN ^ PLASTIC/NONMETALLIC DRUM ^ BAG 224 STORAGE PRESSURE: ^ AMBIENT ^ ABOVE AMBIENT ^ BELOW AMBIENT 225 STORAGETEMPERATURE:O AMBIENT ^ ABOVEAMBIENT ^ BELOW AMBIENT ^ CRYOGENIC %WT HAZARDOUS COMPONENT EHS CAS # 1 zz5 z2~ ^ ves ^ No zzs 2ze 2 230 231 ^ YES ^ NO 232 233 3 Z34 235 ^ Y25 ^ No 236 237 4 238 239 ^ YES ^ NO 240 241 5 Z<2 2a3 ^ Yes ^ No 24a 2a5 _ ` ' t , , ~ ; r i> ~ ii ~~ i R { , ; , a 3 l ~ ~k Y ~ ~ 4 t ~ .. ~ y'a 4 }~~i` ~. t is ''F I a T Fq ~t3 ? 3~: P if ;t'f 4 f3 } ~'M }i Ffk +' kS GNATU G's 'h ~f 3~.tF~ ~kf h''~' f A~' t ~ F i. ~ ~ ~ ~ -~,~ ~ ~ ,. t , . , ~a ~ `~ ~'n ~, ., 4,_ ~, ~,.. ,4 n i ; .C F~. ti ~ :,z~, l .u, -..: , , . ,~ :, k ~ .~ , . „ ~ ,.,.t ..i , , ... ,. .. ..,. .. ... ,.._.. , . . ...., , .,. , .. .. .........r.~ PRINT NAME & TITLE OF AUTHORIZED COMPANY REPRESENTATIVE SIGNATURE DATE 2a6 FD2144 (Rev 01/08) HAZARDOUS MATERIAL MANAGEMENT PLAN '"~` ~~-.-~~.~.-r-„W-~,,. 17~n.y~:, _m~...~ a~~~~."_~ P FP }!~,; `.. p „,~~ry ,}t' F4~r SITE & FACILITY DIAGRAM °'' B B R S P I D F/RB A~ T BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 • Fax: 661-852-2171 Page 2 of 2 ~~ SITE DIAGRAM FACILITY DIAGRAM Business Name: Business Address: ~ NORTH Please indicate direction of North FD2170 (Rev. O1/08) HAZARDOUS MATERIAL MANAGEMENT PLAN BAKERSFIELD FIRE DEPARTMENT . ,y ,.., ¢ , , ` ,{ti ; , .. ~~ s g R s p 1 D prevention Services " .,` ;,~ ~~~ `°`"'~'~ °p' ',~ ~` " ~`~ ; P/RB 1501 Truxtun Avenue, 1~` Floor INSTRUCTIONS ~~.t ~ AI~fM T gakersfield, CA 93301 SITE & FACILITY DIAGRAM ~ Phone: 661-326-3979 • Fax: 661-852-2171 Page 1 of 2 These instructions explain the use of the site diagram and the facility diagram. Normally, small and medium- size businesses will only have to submit a site diagram. If you have subdivided your business into smaller areas because of the complexity or size, then you will be completing an additional detail map, facility diagram, for each of these areas. Include instructions that show the route to your business if it is in a remote location. All diagrams must be on 8~/zx11-inch paper and drawn using a straight edge tool. SITE DIAGRAM INSTRUCTIONS The site diagram is used to show your business and to indicate the businesses that immediately surround your property, usually within 300 feet. If you will be showing specific area detail on facility diagrams, use the site diagram to show an overall layout of the plant. If you will not be submitting facility diagrams, the site map must include all of the following information: 1. Check the box on the top left corner of the form provided that indicated °Site Diagram." 2. Print the name of your business, as shown in your HMMP, on the top of the diagram. 3. Label the location of the hazardous material and identify them by name and type of hazard (flammable liquid, corrosive solid). 4. Label the location of utility shut-ofF points for gas, electric, and water services. 5. Label the location of fire hydrants. 6. Label portions of the building protected by automatic sprinkler systems. 7. Label the direction representing north on the diagram. (The diagram form provided includes a north arrow. ) 8. All labeling and identification on the diagram must be tegible and easily understandable at the scale submitted. Diagrams must be su~ciently legible to produce a legible copy. Try to avoid the use of abbreviations or symbols. If you must use them, provide a legend explaining your system. Maps may be returned for correction if you fail to follow these instructions. FACILITY DIAGRAM INSTRUCTIONS Facility diagrams are supplements to the site diagram. Use them to show the subdivision details of a large business. 1. Check the box in the upper right hand corner of the form provided that indicated ~~Facility Diagram." 2. Print the name of your business as shown on your HMMP. Print the name of the area that this map represents. This name should be the same name that you used on this area's inventory report. 3. Indicate which area the diagram represents and the total number of facility diagrams that you are including. If a map represented the first of four areas, it would be labeled "1 of 4." 4. Follow instructions 3- 8 for site diagrams regarding the specific details to be included on each facility diagram. UNDERGROUND STORAGE TANK FACILITIES PLEASE NOTE: If you operate an Underground Storage Tank (UST) facility, the facility diagram shall also specify the location of the UST continuous leak monitoring system and/or the location where the UST monitoring will be performed. FD2170 (Rev. 01/08) Hazardous Material Inventory - Chemical Description Page 2 of 2 You must complete a separate Hazardous Material Inventory - Chemical Description page for each hazardous material (hazardous substances and hazardous waste) that you handle at your facility in aggregate quantities equal to or greater than 500 pounds, 55 gallons, 200 cubic feet of gas (calculated at standard temperature and pressure) or the Federal threshold planning quantity for Extremely Hazardous Substances, whichever is less. Also complete a page for each radioactive material handled over quantities for which an emergency plan is required to be adopted pursuant to 10 CFR Parts 30, 40, or 70. The completed inventory should reflect ati reportable quantities of hazardous material at your facility, reported separately for each building or outside ad~acent area, with separate pages for unique occurrences of physical state, storege temperature and storage pressure. (NOTE: the numbering of the Instructions follows the data element numbers that are on the UPCF pages. These data element numbers are used for electronic submission and are the same as the numbering used in 27 CCR, Appendix C, and Business Section of the Unified Program Data Dictionary. Please number all pages of your submittat. This helps your CUPA or AA ldentify whether the submittal is complete and if any pages are separated. 1 FACILITY ID NUMBER - This number is assigned by the CUPA or AA. This is the unique number which identifies your facility. 3 BUSINESS NAME - Enter the full legal name of the business. 200 ADD/DELETE/REVISE - Indicate if the material is being added to the inventory, deleted from the inventory, or if the information previously submitted is being revised. NOTE: You may choose to leave this blank if you resubmit your entire inventory annually. 201 CHEMICAL LOCATION - Enter the building or outside/adjacent area where the hazardous material is handled. A chemical that is stored at the same pressure and temperature, in multiple Iocations within a building, can be reported on a single page. NOTE: This information is not subject to public disclosure pursuant to HSC §25506. 202 CHEMICAL LOCATION CONFIDENTIAL - EPCRA - All businesses which are subject to the Emergency Planning and Community Right to Know Act (EPCRA) must check yes to keep chemical location information confidential. If the business does not wish to keep chemical location information confldential check no. 203 MAP NUMBER - If a map Is included, enter the number of the map on which the location of the hazardous material is shown. 204 GRID NUMBER - If grid coordinates are used, enter the grid coordinates of the map that correspond to the location of the hazardous material. If applicable, multiple grid coordinates can be Iisted. 205 CHEMICAL NAME - Enter the proper chemical name associated with the Chemical Abstract Service (CAS) number of the hazardous material. This should be the Intemational Union of Pure and Applied Chemistry (IUPAC) name found on the Material Safety Data Sheet (MSDS). NOTE: If the chemical is a mixture, do not complete this fleld; complete the "COMMON NAME" field instead. 206 TRADE SECRET - Check yes if the Information in this section is declared a trade secret or no if it is not. State requirement: If yes, and business is not subject to EPCRA, disclosure of the designated trade secret information is bound by HSC §25511. Federal requirement: If yes, and business is subjed to EPCRA, disclosure of the designated Trade Secret information is bound by 40 CFR and the business must submit a Substantiation to Accompany Clafms of Trade Secrecy form (40 CFR 350.27) to USEPA. 207 COMMON NAME - Enter the common name or trade name of the hazardous material or mixture containing a hazardous material. 208 EHS - Check yes if the hazardous material is an Extremely Nazardous Substance (EHS), as deflned in 40 CFR, Part 355, Appendix A. If the material is a mixture containing an EHS, leave this section blank and complete the section on hazardous components below. 209 CAS #- Enter the Chemical Abstract Service (CAS) number for the hazardous material. For mixtures, enter the CAS number of the mtxture if it has been assigned a number distinct from its components. If the mixture has no CAS number, leave this column blank and report the CAS numbers of the Individual hazardous components in the appropriate section below. 210 FIRE CO~E HAZARD CLASSES - Describes to flrst responders the type and level of hazardous material which a business handles. This information shall only be provided if the local fire chief deems it necessary and requests the CUPA or AA to collect it. A list of the hazard classes and Instructions on how to determine which class a material falls under are included in the appendices of Article 80 of the Uniform Fire Code. If a material has more than one applicable hazard class, include all. Contact CUPA or AA for guidance. 211 HAZARDOUS MATERIAL TYPE - Check the one box that best describes the type of hazardous material: pure, mixture, or waste. If waste material, check only that box. If mixture or waste, complete hazardous components section. 212 RADIOACTIVE - Check yes If the hazardous material is radioactive or no if it is not. 213 CURIES - If the hazardous material is radioactive, use this area to report the activity in curies. You may use up to nine digits with a floating decimal point to report activity in curies. 214 PHYSICAL STATE - Check the one box that best describes the state tn which the hazardous material is handled: solid, liquid, or gas. 215 LARGEST CONTAINER - Enter the total capacity of the largest container in which the material is stored. 216 FEDERAL HAZARD CATEGORIES - Check all categories that describe the physical and heaith hazards associated with the hazardous material. 217 AVERAGE DAILY AMOUNT - Calculate the average daily amount of the hazardous material or mixture containing a hazardous materlal, in each building or adJacent/outside area. Calculations shalt be based on the previous year inventory of material reported on this page. Total all daily amounts and divide by the number of days the chemical will be on site. If this is a material that has not previously been present at this location, the amount shall be the average daily amount you project to be on hand during the course of the year. This amount should be consistent with the units reported in Box 221 and should not exceed that of maximum daily amount. 218 MAXIMUM DAILY AMOUNT - Enter the maximum amount of each hazardous material or mixture containing a hazardous material, which is handled in a bu(Iding or adjacent/outside area at any one time over the course of the year. This amount must contain at a minimum last year's inventory of the material reported on this page, with the reflection of additions, deletions, or revisions projected for the current year. This amount should be consistent with the units reported in Box 221. 219 ANNUAL WASTE AMOUNT - If the hazardous material being inventoried is a waste, provide an estimate of the annual amount handled. 220 STATE WASTE CODE - If the hazardous material is a waste, enter the appropriate Califomia 3-digit hazardous waste code as Iisted on the back of the Uniform Hazardous Waste Manifest. 221 UNITS - Check the unit of ineasure that is most appropriate for the material being reported on this page: gallons, pounds, cubic feet, or tons. NOTE: If the material Is a federally defined Extremely Hazardous Substance (EHS), all amounts must be reported in pounds. If material is a mixture contalning an EHS, report the units that the material is stored in (gallons, pounds, cubic feet, or tons). 222 DAYS ON SITE - List the total number of days during the year that the material is on site. 223 STORAGE CONTAINER - Check the one box that best descr(bes the type of storage container in which the hazardous material is stored. 224 STORAGE PRESSURE - Check the one box that best describes the pressure at which the hazardous material is stored. 225 STORAGE TEMPERATURE - Check the one box that best describes the temperature at which the hazardous material is stored. 226 HAZARDOUS COMPONENTS 1-5 (% BY WEIGHT) - Enter the percentage weight of the hazardous component in a mixture. If a range of percentages is available, report the highest percentage in that range. (Report for components 2 through 5 in 230, 234, 238, and 242.) 227 HAZARDOUS COMPONENTS 1-5 NAME - When reporting a hazardous material that is a mixture, list up to five chemical names of hazardous components in that mixture by percent weight (refer to MSDS or, in the case of trade secrets, refer to manufacturer). All hazardous components in the mixture present at greater than 1% by weight if non-carcinogenic, or 0.1% by weight if carcinogenic, should be reported. If more than five hazardous components are present above these percentages, you may attach an additional sheet of paper to capture the required information. When reporting waste mixtures, mineral and chem(cal composition should be listed. (Report for components 2 through 5 in 231, 235, 239, and 243.) 228 HAZARDOUS COMPONENTS 1-5 EHS - Check yes if the component of the mixture is considered an Extremely Hazardous Substance as defined in 40 CFR, Part 355, or no if it is not. (Report for components 2 through 5 in 232, 236, 240, and 244.) 229 HAZARDOUS COMPONENTS i-5 CAS - List the Chemical Abstract Service (CAS) numbers as related to the hazardous components in the mixture. (Repeat for 2-5.) 246 LOCALLY COLLECTED INFORMATION - This space may be used by the CUPA or AA to collect any additional information necessary to meet the requfrements of their individual programs. Contact the CUPA or AA for guidance. FD2144 (Rev O1/08) ~HAZARDOUS MATERIAL MANAGEMENT PLAN ~`~ eW'x~,~ir;s~h~rx urt.si.; .~,r" c,;~`. wfi~,?.R,">i',"n '~„a ~'i~:~:.`~~, .;ri~.~.' e.~; i' 8 H R S A I D 6 ,' BUSINESS ACTIVITIES PAGE • ARiu r JU (HAZARDOUS MATERIAL FACILITY INFORMATION) ~ ~ Paae 1 of 1 BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 • Fax: 661-852-2171 ~ ifi 'S~'Y ~( S 4¢~~ ..~.r~~~1 K .~i~'.^'G x~ t ~. . +, l .+"}8 ~J ~~ } ! ~. > 1~. ~4~iro. {3 ~~.:. ~ ~:' ~ . ~ St.~.:~. } 3~ ~: k tl - "C ~~~ 4 I,+. ~~'~ ~L Y ~t ky ~~~'~. ~'* ~rt d:i tf~'~jr6ul~it4^~ ~ s u r S " ~'~t/ ~'4'~rr~~ \~ ~ i (~~~~ ~~ / ; j . ' ~ ~~r y~~'~;~ ~3 ~ - ~ ' , . ~ ~ , t l j ~ ; t : > .~ y ~, .;:^ i r, t~4I FACILITY IDENTIFICATION ~~,,,,~ a ~~~ t~ ~ ~~ ~ } 4 ; ~ ~ ti~~;~f ~~~~ 4 ~ ~ x~a s ~ ~ "~~ ~ ' „ ~ e ~ , ,r~ , ; ,> ~N A ~~ t ,,~ ~ ~ . ,~ y d~u ,Cf,~nr~,. .d e.,~'. a ~.u~ 1-s b~r~' .1.. 4..:, .~.,, .,:a; FACILiTY ID #(for ofRce use only) 3 EPA ID # C/a L DOU 3333 ~~ BUSINESS NAME (FACILITY NAME or DBA) 103 ~ ~ ~ Ma tf~-f- ~ ~~ ~,~~ ~, ~ -c ~ i~ r l~-~if4}{ !~ ~ W~.~U{4 t '~~ ~ G i l~' X~h 1 v%yd h. Ys%.'. ~i ~ k ~:'. ~ '"' J j 4 i f P. l'~, ~ ~~i i ~'~ '~ 3~ 3~'I ~ ~ n., i~ rf ~v~: i~ 1 7~ 7 a a 'z s ~ .:. ~ ' ~~~~' S ~ ~~ + ~ ' . . ,, . . } .}, y Sy y~~y ~s ~ H.v ~ ~ !^ ry s+ ~ x i.,...~ u II ACTIVITIES DECLARATION ~~' : u,F~~, t~ ~~{ 7 }xr~ ,~P~ ~E ~>~ < hs~ ~;F ~~ k , '` ~ : r ~ xl~d ' ~ ~ f ~ ~ ~ ' ~~~ ~ ~z~` .„ , ~ s ~ r ~ ; ~, ~~ ~„ ~;~ ~ ~ .. r ~ t t a.. .. ~ , .., ,_.,,. ~x..., ~~. .a , , ... ,~{. ,w; ~. .~ .., .~:. $„_ , , . ~: ,,. .~. . .~. . . , ,~, _M;~ .. ,~ . , . .~; r,. ~,....z,. ~x . ~.. . ~ ~.., ~~~ , .d ~,. , .~ W . , . ~ . ._ ..... . . ... . ...~, . .~ . , >.., ~ ~. .. , , .~ M_ r DOES Your Facility... / If Yes, Please Complete... lz9 A. HAZARDOUS MATERIAL ^ Yes ~ No . CHEMICAL DESCRIPTION FORM i3o 1. Have on site (for any purpose) hazardous material • HAZARDOUS MATERIAL MANAGEMENT PLAN dt or above 55 gallons for Iiquids, 500 pounds for Minimum required lap nning elements: solids, or 200 cu. ft. for compressed gases (include • Emergency Response Pian Iiquids in AST and UST)? • Maps • Training ~ • Prevention • Certification B. REGULATED SUBSTANCES (RS) ^ Yes No • CHEMICAL DESCRIPTION FORM 131 1. Have on site RS at greater than the threshold • RISK MANAGEMENT PLAN (RMP Submit to USEPA) planning quantities established by the California • CONSOLIDATED COMPLiANCE PLAN Accidental Release Prevention program (CaIARP)? • Incorporating CaIARP Program Elements C. LMDERGROUND STORAGE TANKS (UST) ^ Yes No . UST FACILITY FORM i32 1. Own or operate Underground Storage Tanks? / • UST TANK FORM (one per tank) Yes O No • UST FACILiN FORM 133 2. Intend to upgrade existing or install new UST? • UST TANK FORM (one per tank) • UST INSTALLATION FORM (one per tank) D. TANK CLOSURE/REMOVAL ^ ves rvo • UST TANK FORM (Closure section - one per tank) 1. Need to report closing an UST that held hazardous material or waste? 2. Need to report the closure/removal of a tank that ^ Yes No • UST TANK CLOSURE FORM was classifled as hazardous waste and cleaned onsite? E. ABOVEGROI!ND PETROLEI!M STOReC-E TANKC ^ Yes No • HAZARDOUS MATERIAL MANAGEMENT PLAN (AST] • Incorporating Federal Spiil Prevention Control and Countermeasure 1. Own or operate AST above these thresholds; any (SPCC) Elements pursuant to 40 CFR Part 112. tank capacity is greater than 660 gallons or the total capacity for the facility is greater than 1,320 gallons? F. HAZARDOUS WASTE EPA ID NUMBER - provide on this page 1. Generate hazardous waste? ^ Yes y~ • To obtain EPA ID Number, please phone (916) 324-1781 2. Recycle more than 100 kg/mo of recyclable material at the same location it was generated? ^ Yes ~ rvO . RECYCLING FORM 3. Recycle more than 100 kg/mo of recyclable ^ ves No . RECYCLING FORM material at an off-site location different from the point of generation? 4. Treat Hazardous Waste on site? ^ Yes ~NO . TP FACILITY FORM Fi 5 S b t t i l A i t ? ^ Yes ~ -• TP UNIT FORM (one per unit) • CERTIFIC I nanc . u jec o ssurance requ remen a s AT ON OF FINANCIAL ASSURANCE 6. Consolidate Hazardous Waste generated at a ^ ves rvo . REMOTE WASTE/CONSOLIDATION SITE NOTIFICATION remote site? FORM NOTE: If you checked YES to any part of Sections IIA - IIF above, then in addition to the forms requested above, please submit BUSINESS OWNER/OPERATOR IDENTIFICATION FORM. FD2143 (Rev O1/08) CALIFORNIA ANNOTATED SITE. MAP _ Business Name: JlF ~.v~j #~ ,72L Site Address: Map #: A B C D E F G H I J 1 2 3 4 5 6 7 , . = T'~QA~ . , . . : : ; ~?Q /~/ : : : : . . . . j . . . A ~ .- . ~ . . ~ --- ---- - 8~ ------.------~- -----.-- --rZ---: --- ---------- ~D'~ -.s ~~s- -- ---- - ~ . . . - ~ -- - ` ~ A. . _ ~ . . . ~~ a 1 ~- ?`: - - y - ~ - - ~ uo ~ : : : : ~ : L: ' -~}---- ----- -~-------:------ ~- ------_-- ---r--- --~:-------~------- ------ ~ Z : ~ : : ~: : ~ .. 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FRAZE, FIRE CHIEF GARY HUTTON, SENIOR DEPUTY CHIEF ADM7NIS1ftATION TYLER HARTLEY, DEPUTY CHIEF oveaanonsrn+uNwc DOUG GREENER, DEPUTY CHIEF FlRE SAFEiV/PREVENTION SERVI~S HOWARD H. WINES, III, DIRECTOR PREVENTION SERVICES PiRH SI1F8T1 SERVICES ~ ENViRONME1frAL SERViCES 1501 Truxtun Avenue Bakersfield, CA 93301 OFFICE: 661-326-3979 FAX: 661-852-2171 Dear Business Owner: This packet contains important information regarding your business and the requirements of Hazardous Material Inventory Regulations. Both State and Federal laws may require that your business complete a Hazardous Material Management Plan (HMMP). Please read all the enclosed information carefully. Failure to comply with any portion of the Business Plan requirements may result in Civil Liabilities of up to $2,000 for each day in which violation occurs. WHAT BUSINESSES MUST COMPLY If you handle, use, store, or dispose of hazardous substances at any time during the year in excess of the minimum reporting quantities you must submit a plan. Typical everyday hazardous material you may find in your facility may include, but are not limited to: compressed gasses; fuels - all types, including propane; solvents - most solvents would be hazardous material; oils - new and waste; thinners; caustic or corrosive material; poisonous or toxic material, and radioactive material. Minimum State reporting quantities for hazardous material are: • 55 gallons for liquids • 500 pounds for solids • 200 cubic feet (at standard temperature and pressure, for gasses) For all acutely hazardous material the minimum reporting quantities are found on the list of Extremely Hazardous Substances on the current EPA list (Vol. 52 No. 77 of the Federal Register.) This list is available at the O~ce of Prevention Services of the Bakersfield Fire Department, 1501 Truxtun Avenue, Bakersfietd, California 93301. For explosives and hazardous waste, any quantity is reportable. Your reporting requirements are either the State quantities or the Federal (threshold planning quantity). WHICHEVER IS LOWER! WHAT BUSINESSES ARE EXEMPT If you do not handle hazardous material or if the quantities of hazardous material are below the minimum reporting quantities at all times during the year, you are exempt. Hazardous material which are stored in transit or temporarily maintained in a fixed facility for less than thirty (30) days during the course of transportation are exempt from the inventory requirements of the law. NOTE: Hazardous material contained solely in a consumer product for direct distribution to, and use by, the general public are NOT exempt from the reporting requirements of the law per this Administering Agency.) HOW DO BUSINESSES COMPLY Businesses that are required to comply with requirements of Chapter 6.95 of California Health and Safety Code must submit a plan. This business plan consists of: 1. Emergency Response Plans and Procedures. 2. Inventory of Hazardous Material. 3. Training Program for Employees. The forms for completing the Hazardous Material Management Plan are attached to this letter. By correctly filling in this business plan, you satisfy both the Federal Requirements (Tier I and Tier II Inventory Requirements of SARA Title III) as well as the California Requirements of Chapter 6.95 of the `California Health and Safety Code. Business owners are urged to read and become familiar with Chapter 6.95 of the California Health and Safety Code. Copies are available at the Office of Prevention Services of the Bakersfield Fire Department, 1501 Truxtun Avenue Bakersfield, California 93301. The completed business plan is required to be submitted within 30 days of receipt of this letter. On-site inspections are required to ensure compliance with the law. If you have any questions or need assistance with completing the Business Plan, please call Manar Haddad at 326-3464. J~tr~a~ f~a Z~ anars~r,~~at ..~%Lo~e Jfur.sa ~ C~~~r~ ., i , ~ HAZARDOUS MATERIAL MANAGEMENT PLAN INSTRUCTIONS BUSINESS OWNER/OPERATOR ID FORM (HAZARDOUS MATERIAL FACILITY INFORMATION) S B R S A 1 D FIRB A~ T Page i of 1 BAKERSFIELD FIRE DEPARTMENT Prevention Services 1501 Truxtun Avenue, 1~` Floor Bakersfield, CA 93301 Phone: 661-326-3979 • Fax: 661-852-2171 I. FACILITY IDENTIFICATION: Enter the reporting period (year beginning and ending) for the facility information. Enter the business name and site address and phone number of your business. Do not use P.O. Box numbers. Enter the Dunn & Bradstreet or Federal Tax Identification number for your business. Enter the Standard Industrial Classification (SIC) number for your business. Each type of business has a Standard Industrial Classification code number. Some common SIC codes are listed on the bottom of this page. Other SIC codes may be obtained from your worker's compensation insurance forms, the State of California Employment Development Department, or by calling our office at 326-3979. Enter the name and phone number of the person responsible for operating the business. II. OWNER INFORMATION: List the legal business owner or corporation name and provide the headquarter address or residential address if owned by an individual and phone number. III. ENVIRONMENTAL CONTACT: Identify the person who is primarily responsible for environmental compliance at the business. This person may be either the business owner, one of the emergency contacts, an environmental manager, or consultant. IV. EMERGENCY CONTACTS: List the name, title, and phone numbers of two people at the business who can respond if the Bakersfield Fire Department requires additional information or other assistance. These contact persons must have keys or access to all areas of the facility, be available for emergency call-outs, and have decision-making authority to call on other resources (such as hazardous waste clean-up companies) as necessary. V. CERTIFICATION: The business owner or operator must sign, date, and also identify the document preparer. COMMON STANDARD INDUSTRIAL CLASSIFICATION (SIC) CODES 0111 Wheat production 0541 Grocery store 5531 Auto & home supply store 0115 Corn production 0724 Cotton ginning 5541 Gasoline service station 0131 Cotton production 1541 Dry cleaning ~5821 Eating establishment 139 Field crops, except cash grains 2851 Paint manufacture 5813 Drinking establishment (alcohol) 0161 Vegetables & melons 2911 Oil refinery ~5983 Fuel oil dealer 0172 Grapes !3441 Welding fabrication-structural 'S984 LPG dealer 0173 Tree nuts ,3443 Welding fabrication-boiler 7342 Pest control ~0174 Citrus fruits ~3569 Machine shop ~7532 Auto body, upholstery repair, paint 0175 Deciduous tree fruits ~222 Cold storage 17533 Auto exhaust repair 0179 Other tree fruits & nuts 4925 Compressed gas supplier !7536 Auto glass replacement 0192 General farms, rimaril cro 'S093 Automobile salvage '7537 Auto transmission re air 0241 Dairy farms ;5169 Chemical supply ~7538 General auto repair 0252 Chicken eggs I5511 Motor vehicle dealer (new & used) ;7542 Car wash 0291 General farm, livestock & animals ~5521 Motor vehicle dealer (used only) !8071 Chemical laboratory ~ FD2141 (Rev 01/08) ~ .. ~, 1 .. ~ ~~ MSDS Code: 778615 Status: Finai ;~~ ~~~~~~~~ 1. PRODUCT AND COMPANY IDENTIFICATION 76 Super Synthetic Blend Motor Oii Product Name: 76 Super Synthetic Blend Motor Oil Product Code: 1043421, 1043441, 1043226 Intended Use: Crankcase Oil Synonyms: 76 Super Synthetic Blend Motor Oil, SAE 5W-20 76 Super Synthetic Blend Motor Oil, SAE 5W-30 76 Super Synthetic Blend Motor Oil, SAE 10W-30 Chemical Family: Responsible Party: Customer Service: Technical Information: Page 1/7 Date of Issue: 22-Feb-2005 MATERIAL SAFETY DATA SHEET Petroleum Hydrocarbon 76 Lubricants . A Division of ConocoPhillips 600 N. Dairy Ashford Houston, Texas 77079-1175 888-766-7676 800-435-7761 The intended use of this product is indicated above. If any additional use is known, please contact us at the Technical Information number listed. EMERGENCY OVERVIEW 24 Hour Emergency Telephone Numbers: Spill, Leak, Fire or Accident Call CHEMTREC: North America: (800) 424-9300 Others: (703) 527-3887 (collect) California Poison Control System: (800) 356-3219 Health Hazards/Precautionary Measures: Avoid contact with skin and clothing. Wash thoroughly after handling. Physical Hazards/Precautionary Measures: Keep away from all sources of ignition. Appearance: Clear, Amber Physical Form: Liquid Odor: Characteristic petroleum NFPA 704 Hazard Class: HMIS Hazard Class: Health: 1 (Slight) Health: 1 (Slight) Flammability: 1 (Slight) Flammability: 1 (Slight) Instability: 0(Least) Physical Hazards: 0(Least) MSDS Code: 778615 Status: Final Page 2/7 Date of Issue: 22-Feb-2005 2. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Com onent / CAS No: Percent % ACGIH: OSHA: NIOSH: Other: inc Compound(s) PROPRIETARY 0.5-1.5 NE NE NE NE NON-HAZARDOUS COMPONEN TS Com onent / CAS No: Percent °/a ACGIH: OSHA: NIOSH: Other: Lubricant Base Oil (Petroleum) 79-83 5mg/m3 TWA 5 mg/m3 TWA 2500 mg/rn3 IDLH as Oil Mist, if ARIOUS 10 mg/m3 STEL Generated 5 mg/m3 NOHSC TWA dditives 17-21 NE NE NE NE PROPRIETARY The base oil for this product can be a mixture of any of the following highly refined petroleum streams: CAS 64741-8&4; CAS 64741- 89-5; CAS 64741-96-4; CAS 64741-97-5; CAS 64742-01-4; CAS 64742-52-5; CAS 64742-53-6; CAS 64742-54-7; CAS 64742-55-8; CAS 64742-56-9; CAS 64742-57-0; CAS 64742-62-7; CAS 64742-63-8; CAS 64742-65-0; CAS 72623-83-7; CAS 72623-85-9; CAS 72623-86-0; CAS 72623-87-1 Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. 1 %=10,000 PPM. NE=Not Established All components are listed on the TSCA inventory. 3. HAZARDS IDENTIFICATION Potential Health Effects: Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation (Breathing): No information available. Studies by other exposure routes suggest a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the nose and throat, irritation of the respiratory tract, irritation of the digestive tract, nausea, diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Cancer: Inadequate evidence available to evaluate the cancer hazard of this material. See Section 11 for carcinogenicity information of individual components, if any. Target Organs: No data available for this material. Developmental: No data available for this materiai. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. 4. FIRST AID MEASURES Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If symptoms persist, seek medical attention. r ~ MSDS Code: 778615 Status: Final Page 3/7 Date of Issue: 22-Feb-2005 Skin: Wipe material from skin and remove contaminated shoes and clothing. Cleanse affected area(s) thoroughly by washing with mild soap and water and, if necessary, a waterless skin cleanser. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing): If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: High-pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing extemal wound. Often these injuries require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. 5. ~IRE-FIGHTING MEASURES Flammable Properties: Flash Point: OSHA Flammability Class: NFPA Flammability Class: LEL%: UEL%: Autoignition Temperature: 365°F / 185°C (PMCC) (minimum) Not regulated No data No data No data No data Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or conflned spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant (see Section 8). Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and.natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). MSDS Code: 778615 StBtus: Finai Page 4/7 Date of Issue: 22-Feb-2005 7. HANDLING AND STORAGE Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Sections 2 and 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be• completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though no symptoms or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Storage: Keep container(s) tightly closed. Store only in approved containers. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Storage temperatures above 113°F inay lead to thermal decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: If current ventilation practices are not adequate to maintain airbome concentrations below the established exposure limits (see Section 2), additional engineering controls may be required. Personal Protective Equipment (PPE): Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits (see Section 2). Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any o4her circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 9. PHYSICAL AND CHEMICAL PROPERTIES Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Appearance: Clear Amber Physicai Form: Liquid Odor: Characteristic petroleum MSDS Code: 7786~5 Status: Final Page 5l7 Date of Issue: 22-Feb-2005 Odor Threshold: No data pH: Not applicable Vapor Pressure (mm Hg): <1 Vapor Density (air-1): >1 Boiling Point: No data Solubility in Water: Negligible Partition Coefficient (n-octanol/water): No data Specific Gravity: 0.85-0.87 Bulk Density: 7.08-7.24 Bulk Density Units Ibs/gal Viscosity cSt @ 100°C: 8.1-11.5 Viscosity cSt @ 40°C: 44-70 Evaporation Rate (nBuAc=1): <1 Flash Point: 365°F / 185°C Test Method: (PMCC) (minimum) LEL%: No data UEL%: No data Autoignition Temperature: No data 10. S'I'ABILITY AND REACTIVITY Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials): Avoid contac~ with strong oxidizing agents, reducing agents. Hazardous Decomposition Products: Combustion can yield carbon, nitrogen, suffur, phosphorus, and zinc oxides. Hydrogen sulfide and alkyl mercaptans may also be released. Thermal decomposition may produce hydrogen sulfide and other sulfur-containing gases at temperatures greater than 113°F. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Chronic Data: Lubricant Base Oil (Petroleum) - CAS: VARIOUS Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and improve performance characteristics. Ail of the oils meet the IP-346 criteria of less than 3 percent PAH's and therefore none are listed as a carcinogen by NTP, IARC, or OSHA. Acute Data: Lubricant Base Oil (Petroleum) - CAS: VARIOUS Derma/ LD50 = >2 g/kg LC50 = No information available Ora/ LD50 = >5 g/kg Additives - CAS: PROPRIETARY Derma/ LD50 = No information available LC50 = No information available Oral LD50 = No information available Zinc Compound(s) - CAS: PROPRIETARY Derma/ LD50 = No information available LC50 = No information available Oral LD50 = No information availabie MSDS Code: 778615 Status: Finai Page 6/7 Date of Issue: 22-Feb-2005 12. ECOLOGICAL INFORMATION Not evaluated at this time. 13. DISPOSAL CONSIDERATIONS This material under most intended uses would become used oil due to contamination by physical or chemical impurities. RECYCLE ALL USED OIL. While being recycled, used oil is regulated by 40 CFR 279. Use resulting in chemical or physical change or contamination may also subject it to regulation as hazardous waste. Under federal regulations, used oil is a solid waste managed under 40 CFR 279. However, in Califomia, used oil is managed as hazardous waste until tested to show it is not hazardous. Consult state and local regulations regarding the proper handling of used oil. In the case of used oil, the intent to discard it may cause the used oil to be regulated as hazardous waste. Contents should be completely used and containers emptied prior to discard. Rinsate may be considered a RCRA hazardous waste and must be disposed of with care and in compliance with federal, state and local regulations. Large empty containers, such as drums, should be returned to the distributor or a drum reconditioner. To assure proper disposal of small empty containers, consult with state and local regulations and disposal authorities. 14. TRANSPORTATION INFORMATION DOT Proper Shipping Name: Not classified as hazardous Note: Material is unregulated unless in container of 3500 gallons or more, then provisions of 49 CFR Part 130 apply for land shipment. IMDG Shipping Description: Not regulated ICAO/IATA Shipping Description: Not regulated 15. REGULATORY INFORMATION U.S. Regulations: EPA SARA 311/312 (Title III Hazard Categories~, Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No SARA - Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372: Zinc Compound(s) ................PROPRIETARY................0.5-1.5% ~PA (CERCLAI Reportabie Quantitv (in pounds~ --None Known-- CERCLAISARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds~ This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372: -- None Known - California Proposition 65: Waming: This material contains the following chemicals which are known to the State of California to cause cancer, bi~th defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Used engine oils, while not a component of this material, is on the Proposition 65 list of chemicals known to the State of California to cause cancer. Carcinogen Identification: MSDS Code: 778615 Status: Final Page 7/7 Date of Issue: 22-Feb-2005 This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for carcinogenicity information of individual components, if any. Used motor oil has been identified as a possible skin carcinogen by IARC. TSCA: All components are listed on the TSCA inventory. International Regulations: Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Domestic Substances List: Listed WHMIS Classification: Not regulated 16. OTHER INFORMATION Issue Date: 22-Feb-2005 Previous Issue Date: 08/OS/2004 Product Code: 1043421, 1043441, 1043226 Reason for revision: Additional product grades added/removed - See Synonyms, SECTION 1 No change to hazards. MSDS Code: 778615 Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. l ~ ~ 76 Super High Mileage ~~' ~"~'~~~~~ Synthetic Blend Nfotor Oil (All ~ Grades) Material Safety Data Sheet , . w ~ , ~~ ~ . ~~~~ ~ ~ , ~ ~z~~~ ~~ ~~ 1 1e~~;~~P~ROD,U:C~Y~AND~COMPANY~IDENTI~IC~A~T"il~~N~~~,,~~.~;~~~~~~~, K=~~~~N~~~ ~~,~~;~,::,~~., ~~~~~~~`~~~,~~~ ~~~~~~ ~~~.:~ Product Name: 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) MSDS Code: 778732 Synonyms: 76 Super High Mileage Synthetic Blend Motor Oil, SAE 5W-30 76 Super High Mileage Synthetic Blend Motor Oil, SAE 10W-30 Intended Use:~ Crankcase Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-255-9556 MSDS Information: Intemet: http://w3.conocophillips.com/NetMSDS/ ~ Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours) Califomia Poison Control System: 800-356-3219 ,. . _, F r .^ : y~ .y ~.:.:s ~ ' n ~ ' ~",iz » ~ . :~~~H_ ,F ~ RDS~ IDENTIFICATtO ~~ ~ ~ ~~ ~ ~ ,~~ ~-~~ ~ ~~ ~~~~~,r~ a > ~~~~~ ~~° r' .o. . , ..~_ _ ~ . ~=..~ .., f ~ ,. ~~.'~. ~ ' ~~~;. ~~~~~~,:_~~ k..~5~~~~~ ..~~~. Mkea~~ ~ ~s. ~ ~~i , ~ ..~ ~;~~~~.'~'`~~: ~'~t.~an~. *~5,~"':r This material is not considered hazardous according to OSHA criteria. o. Appearance: Clear amber Physical Form: Liquid Odor: Characteristic petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness and a burning sensation. Not expected to be a skin irritant under normal conditions of use. Prolonged or repeated contact can defat the skin, causing drying and cracking of the skin, and possibly dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation (Breathing): Expected to have a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. See Section 11 for additional Toxicity Information. 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (Ali Grades) Page 1/7 Date of Issue: 03-Apr-2007 Status: Finai 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 2/7 Date of Issue: 03-Apr-2007 Status: Finai ,~.~CO.MPOS:IT,,ION~/~I.NF~ORMA~TION.:ON~iNGREDIENTS~,,_,s~~;~~;~~~k~,.~~.~k~~~X~~~ y~~~ ~~~ "~ ~ ~ ~.~~~ ~ ~ ~ _~, ~ . ~~. ~`~~~r ~~o.~~~~;,.~ Lubricant Base Oil Petroleum VARIOUS 74 - 79 dditives PROPRIETARY 21 - 26 ,- . ~~PIRS'T~ AID~MF~,ISUR~S~~ ~~` ~ "~~~`~` ~ ~ ~,~~~t ~ ~~~~ ~~ , 3~ ~ ~~ ~ ~ ~ ~ ;~ ~,~~ ~ ~~ ~ ~ ; i.;~ ~~ ~ ~ a~ ~a ~ '< ~ ~ ~ ~ ~~ ~ 3 ~ ~ .~•_.., ,.. ., .,%~... _ .d_.. ...,..~r'' ,.'f~u,."~{:}F..&~ :~~,~,',~k.s.,~~,aa: :.r~` ~+ '~^ • ...~:~ s~k v ;x~a.. _~'k..~_ .,s . ,.~b. . :`~ ~~ ~ Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. 5~' `~~F1RE FIG'HTING~MEAS § RES~~ ~`~~ ~ ~~`~_` _z ~~ ~:~ ~, ~~ ~~ y ~ ~. ~sti•s~~~~ ~~,.<~ ~~,~~,~ 4 . ~ ~~ ..~tr..n,..>... ...L.. ...,. ........~....~._.... _ ...,_ ia....~.~_._..~~~.ix~"i~'~~:`. ..~..qsS~:~.~~rsc.' ~, rs.k"'~a~~~~~~'~,e7'~s.ari~'~:`.9~~~~~~~s`~~.w..~:ra~~~a`~`.. .~;?.;f~~. .+~~ NFPA 704 Hazard Class Health: 1 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe) Unusual Fire 8 Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Vapors are heavier than air and can accumulate in low areas. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors.and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits 6~= ~ACCIDENTAL~ RE~EASE~IIIIEASURES~~.~~~~H ~..;.~~. ~;~~~ ~~~ t.... ~` ..~~.~. ....;~~~ ~'. ~~,.~`~~~~~~~~',~~: ~. ~~.~~~ ~>~~;~_~~,~ Personal precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Spiil precautions: Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). Environmental precautions: Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 3/7 Date of Issue: 03-Apr-2007 Status: Final Methods for cleaning up: Immediate cleanup of any spill is recommended. Notify fire authorities and appropriate federal, state, and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). , .~~~=~H~i4NDLING~`AND~S70.RAGE~`~~`~~~;~ s~ ~~~ ~ #~~ ~ ~ ~ ~ t ~~~ ~ ~ ~~~~~~~~ ~ -~:~ .~ . ~ s# L . . . . .... . .~ ...., z . .. ~'~#~f° ~ ~e,n~a; ~'~~~t~ ~~u .~5.~,.'~',~~ ~'~«~~~v~'.-'~„.'~y~~ .5~ ~~~aka~"" ~e„Y'v~.. E~~ . ~4~~.~ .~. Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Section 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparics, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with governmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Used motor oils have been shown to cause skin cancer in mice after repeated application to the skin without washing. Brief or intermittent skin contact with used motor oil is not expected to cause harm if the oil is thoroughly removed by washing with soap and water. Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. ~~ ~ ~ ~~ ~ ~ ~ ~ ~ ~`~EXPOSU,RE°CONT~2flLS,/,PERSONA~,P ,O~TECTICIN ' ~`~ ~~z ~~~_ ~"~ ~~ `=~ ~3~ ~ ~-~~~ .~ ~ ~ '~ ~ ~ ~ ~ ~ ' ~ x ~ ~ ~~ . ~ ~',~a~,~.~s~,~, . ~~~.~ ~~.. ~ ~ •~~s ~i kv ~ " z~ ~ ~ ~<~~hCorri`:o~ent..~ ?,.~ ~ ~ * ~% ~x ~ F ~,~~ ; t t' ~ ~`~: .~~~:~;4~~,~^kCGiH ,~ ~~,~;:~ ~.. h a ~~ '~~~,5~~~,..:~~'~ 1 ~ ~ ~~,~ ~az~.~t... ~"~'~'~~'`s ~. ~~` ~ :~~ ant t :~ ,~r:E,~;~~ ~ u~ ~Other~~~~ .b~a. Lubricant Base Oil (Petroleum) TWA: 5mg/m3 TWA: 5 mg/m' - STEL: 10 mg/m3 as Oil Mist, if Generated as Oil Mist, if Generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits additional engineering controls may be required. Personal Protective Equipment (PPE): Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled, such as nitrile, is advised to prevent skin contact and possible irritation ~see manufacturers literature for information on permeability). Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 4/7 Date of Issue: 03-Apr-2007 Status: Final , ~ 9~~,~PHYSICAL~,AN~D~~CHEMICAL~PROPERTIES~~~ .~ ~ `~ `~~~~ ~~~k~~~ y~`'` ~~ ~ ~~~~ ~7~~~~ ,;~~ . . ~ .a ~ , .s. ~s. . ~~ ~,~_,~.~,"~ .: , _ ~ ~. ,.~r. . h ~~. ~~~ ~~ - .~.. ~~ ~~... ~ x~~".;~ ~ ~ Note: Unless othervvise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Appearance: Physical Form: Odor: Odor Threshold: pH: Vapor Pressure: Vapor Density (air-1): Boiling PoinURange: Melting/Freezing Point: Solubility in Water: Partition Coefficient (n-octanol/water) (Kow) Specific Gravity: Bulk Density: Viscoslty: Percent Volatile: Evaporation Rate (nBuAc=1): Flash Point: Test Method: LEL (vol °/a in air): UEL (vol °/, in air): Autoignition Temperature: Clear amber Liquid Characteristic petroleum No data . Not applicable <~ >1 No data No data Negligible No data 0.86 - 0.88 @ 60°F (15.6°C) 7.16 - 7.33 Ibs/gal 11.1 - 12.2 cSt @ 100°C; 65 - 82 cSt @ 40°C Negligible <1 Minimum 365°F / 185°C Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 No data No data No data ~~~ ~ ~ b a ~ ~ ~. ~t ~ 1;Q 9 ~.STABILIT~YF AND~REAC~TIU;iT~Y~~~~'~~~,.r~~~.~~~~~ .~ ~ ~~~~~~~~~~~~,~;~~~_~~~~ . ~~~~ ~~~~~ ~.~ , Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidizing agents and strong reducing agents. Hazardous Decomposition Products: Combustion can yield carbon, nitrogen, sulfur, phosphorus, and zinc oxides. Hydrogen sulfide and alkyl mercaptans may also be released. During use in engines, contamination of oil with low levels of hazardous combustion products (polycyclic aromatic hydrocarbons) may occur. Hazardous Polymerization: Will not occur. ~~~~~ ~TOXICOL'QGICALxINFfJRMA~Ti,OIV~~~~~~~~~~-.~~~~ .~ ~ ~~~~~~~~~,~ : ,~~,~-~~~, ~ ti ,.~~ ;~ _ ~~~~ ~~ ~~ ~ ~~a7 ..~ . _t %n s>x ~n 3 s .%, n '~. ~.59~ ~a ~ ~~ .~ Y{~ •,, ~'~`~~a~~' 3 "'.~Tna~h,'~~' w.. Chronic Data: Lubricant Base Oil (Petroleum) Car~cinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and/or dewaxing to remove aromatics and improve performance characteristics. They contain low concentrations of PAH's and none have been identified as a carcinogen by NTP, IARC or OSHA. Acute Data: ~ ~Lubricant Base Oil (Petroleum) ~ >5 g/kg ~ >2 cl/kq No Dafa 1°2 ~,~ECOLOGICAL`~INFC3RMATIO.N.,, ; ~,;~~~~ ~>-~~ * ~~ ~ ~ ~ E K~ ~~~ ~~°~ ~ ~~~~ ~ x': ~~4¢~ <~~~~~~; ~ , .. ..., ,,.~ . < ~. ~. ~.. . ~.•., ,.. ~ .~ s.~ ~ . . . ~ ., . ~. . ~ . ~ . ,, ,.~r~.. 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 5/7 Date of Issue: 03-Apr-2007 Status: Final Lubricant oil basestocks are complex mixtures of hydrocarbons (primarily branched chain alkanes and cycloalkanes) ranging in carbon number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are found only at very low concentrations. Volatilization is not significant after release of lubricating oil basestocks to the environment due to the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process. Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities to fish, Daphnia, Ceriodaphnia and algal.species are above 1000 mg/I using either water accommodated fractions or oil in water dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that acute toxicity would not be observed with these substances due to low water solubility. Results from chronic toxicity tests show that the no observed effect level (NOEL) usually exceeds 1000 mg/I for lubricant base oils with the overall weight of experimental evidence leading to the conclusion that lubricant base oiis do not cause chronic toxicity to fish and invertebrates. Large volumes spilis of lubricant base oils into water will produce a layer of undissolved oi{ on the water surface that will cause direct physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments. Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch. Extensive experience from laboratory and field trials in a wide range of crops has confirmed that littie or no damage is produced as a result of either aerosol exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%. ~ 1'3~~~DISP~USAL GONSIDER~ATtONS;< .~,-~~5~~,~ ~ ~~~~~ ~ ~ ~ ~~~~Z ~ ~~ ~y ~ s, X~ ~~F,~ ~ ~ ,, ~ ~, ' ~ - ~~~~o ~ ~~~ ~ ~ ;... ~C~.~ _ .~..R._ ___~ e. _ ~~ . .~ _ __ >~~~ .~ri... ~',.~;~.,~~ ~ ~ _~~~~~. ,s~~~,. ~ ~~ ~ _ , ~_ .~ ~~ . ,~ . ~. . ~~. ~" The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oi~" due to contamination by physical or chemical impurities. Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers shouid be emptied prior to discard. 1:4~~,TR~ANSP~RTAT~JC~N~IPIFB~RMATIUN,~~`~~~'~ ~x ;~~~ "~~ ~~,~~~4~~~~~°~~~ ~;~ .~'~ ~ ~u~`~=`~ ~.u~_~'~~.w~~: ~ = y~,~~~~~° U.S. Denartment of Transportation (DOT~ Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) ~ernationai Maritime Dangerous Goods~IMDG~ Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. International Civil Aviation Org / International Air Transport Assoc (ICAO/IATJ UN/ID #: Not regulated Note: Additional Federal compliance requirements may apply. See 49 CFR 171.11. LTD. QTY Passenger Aircraft Cargo Aircraft Only Packa in Instruction #: --- __ ___ Max. Net Q. Per Packa e: --- ___ ___ 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 6/7 Date of Issue: 03-Apr-2007 Status: Final . ~KS ~ ~ a ~ ' ;lr`.~ ~~`"'~ ~ ~~:zF~~a~ +d~-'r'.~Y~~, x a ~,~ ..'~a~ s ~` ~.~aee£'~'~ ~ s,~:., 1=5 °~ REG,ULATORY~INFO ,RMA~TI,OAt,~~~~~~~~~~~ ~ ... ~;~,. s ~ ~~ .. ~ ~ '<`~~~"?~~~ "~~ -`' a~~~'~-~,,3.:~~~~~~ ~~~1 CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPas (inpounds~. This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. C~,RCLAISARA - Section 317/312 (Title III Hazard Categories~ Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLAlSARA - Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372: ~PA (CERCLA) Reportable Quantity lin pounds-: This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm. Used engine oil, while not a component of this material, is on the Proposition 65 list of chemicals known to the state of California to cause cancer. Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class None National Chemical Inventories: All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are listed on the Canadian DSL. U.S. Export Control Classification Number: EAR99 ~ .E ~, :;.€,~+a~'c€.~'~' ~~~ ° .,n ~~.'~~`~ ~'+4.Wq.,.Y-,~/ ~ b ;" ra~, .n .. t ~,'~ u ~ ' ~ r~` " q"- # n.;. ~,~ 1~6.~=~OTHER~~INFORMATION~;~~=.~x..~~s..~~~~~~~~.,~,~~~~~~~~ ~~~,~~',~~ ~~~~~~`~~ ~~~~ ~~~~°~~~~~>,~~~~,F~.~~ ~~ ,~ ..,s,"; ~Y~,xY~..~,.. ~ r .s...~„y ..I,v _ ~ .~~5 ~.. .~~~~ f~~,.~'~." Issue Date: Status: Revised Sections or Basis for Revision: MSDS Code: 03-Apr-2007 Final Regulatory infoRnation (Section 15) 778732 MSDS Legend: ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service Registry; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; IARC = Intemational Agency for Research on Cancer; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) .1 778732 - 76 Super High Mileage Synthetic Blend Motor Oil (All Grades) Page 7/7 Date of Issue: 03-Apr-2007 Status: rinal Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. MSDS Code: 778846 Status: Final Page 1/7 Date of Issue: 31-Aug-2006 PHILLIPS ~~ i i ~~~~ ~ MATERIAL SAFETY DATA SHEET Super ATF 1. PRODUCT AND COMPANY IDENTI~ICATION Product Name: Intended Use: Chemical Family: Responsible Party: Customer Service: Technical Information: Super ATF Transmission Oil Petroleum Hydrocarbon ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 888-766-7676 800-435-7761 Emergency Overview 24 Hour Emergency Telephone Numbers: Spill, Leak, Fire orAccident Call CHEMTREC: North America: (800) 424-9300 Others: (703) 527-3887 (collect) Califomia Poison Control System: (800) 356-3129 Health Hazards/Precautionary Measures: A component may cause an allergic skin reaction. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Physical Hazards/Precautionary Measures: Keep away from all sources of ignition. Appearance: Red Physical Form: Liquid Odor: Characteristic petroleum NFPA 704 Hazard Class Health: 2 Flammability: 1 Instability: 0 Legend: 0(Least), 1(Slight), 2(Moderate), 3(High), 4(Extreme) 2. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Component Concentration ACGIH: OSHA: NIOSH: Other: V1It % Ikoxylated Long-Chain Alkyl < 0.2 NE NE NE NE mine Pro rieta MSDS Code: 778846 Page 2/7 Status: Final Date of Issue: 31-Aug-2006 NON-HAZARDOUS COMPONEN TS Component Concentration ACGIH: OSHA: NIOSH: Other: wt % Lubricant Base Oil (Petroleum) 84 - 88 5mg/m' TWA 5 mg/m3 TWA 2500 mg/m' IDLH as Oil Mist, if ARIOUS 10 mg/m3 STEL Generated 5 mg/m3 NOHSC TWA dditives 12 - 16 NE NE NE NE PROPRIETARY Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. 1 %=10,000 PPM. NE=Not Established 3. HAZARDS IDENTIFICATION Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis (inflammation). A component of this material may cause an allergic contact dermatitis (redness and itching of the skin). No harmful effects from skin absorption are expected. Inhalation (Breathing): No information available. Studies by other exposure routes suggest a low degree of toxicity by inhalation. Ingestion (Swallowing~: No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Cancer: There is inadequAte information to evaluate the cancer hazard of this material. See Section 11 for information on the individual components, if any. Target Organs: No data available for this material. Developmental: No data available for this material. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. 4. FIRST AID MEASURES Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing with mild soap and water. If irritation or redness develops, seek medical attention. Inhalation (Breathing): If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing di~culties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. ~nhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. MSDS Code: 778846 StBtus: Final 5. FIRE-FIGHTING MEASURES Flammable Properties: Page 3/7 Date of Issue: 31-Aug-2006 Flash Point: 315°F / 157°C (minimum) Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 OSHA Flammability Class: Not applicable LEL (vol % in air): No data UEL (vol % in air): No data Autoignition Temperature: No data Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Vapors are heavier than air and can accumulate in low areas. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). MSDS Code: 778846 Status: Final Page 4/7 Date of Issue: 31-Aug-2006 7. HANDLING AND STORAGE Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Sections 2 and 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Englneering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits (see Section 2), additionai engineering controls may be required. Personal Protective Equipment (PPE): Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits (see Section 2). Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirators use. Skin: The use of gloves impervious to the specific material handled, such as nitrile, is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Other Protective Equipment: A source of clean water should be available in the worlc area for flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 9. PHYSICAL AND CHEMICAL PROPERTIES Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Appearance: Physical Form: Odor: Odor Threshold: pH: Vapor Pressure (mm Hg): Vapor Density (air-1): Boiling PoinURange: Red Liquid Characteristic petroleum No data Not applicable <~ >1 No data MSDS Code: 778s46 StBtus: Final Page 5/7 Date of Issue: 31-Aug-2006 9. PHYSICAL AND CHEMICAL PROPERTIES MeltinglFreezing Point: No data Solubility in Water: Negligible Partition Coefficient (n-octanollwater) (Kow): No data Specific Gravity: 0.86-0.87 Bulk Density: 7.16-7.24 Ibs/gal Viscosity: 7.1 - 8.1 cSt @ 100°C; 30.0 - 40.0 cSt @ 40°C Percent Volatile: Negligible Evaporation Rate (nBuAc=1 ~: <1 Flash Point: 315°F / 157°C (minimum) Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 LEL (vol % in air): No data UEL (vol % in air): No data Autoignition Temperature: No data Decomposition Temperature: No data 10. STABILITY AND REACTIVITY Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials~: strong oxidizing agents. Hazardous Decomposition Products: Combustion can yield oxides of carbon, nitrogen, sulfur and phosphorus. Methacrylate monomers may also be formed. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Chronic Data: Lubricant Base Oil (Petroleum) VARIOUS Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and/or dewaxing to remove aromatics and improve performance characteristics. They contain low concentrations of PAH's and none have been identified as a carcinogen by NTP, IARC or OSHA. Acute Data: Lubricant Base Oil (Petroleum) VARIOUS Dermal LD50= >2 g/kg lnha/afion LC50= No information available Ora/ LD50= >5 g/kg MSDS Code: 778846 Page 6/7 Status: Final Date of Issue: 31-Aug-2o06 12. ECOLOGICAL INFORMATION Lubricant oil basestocks are complex mixtures of hydrocarbons (primarily branched chain alkanes and cycloalkanes) ranging in carbon number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are found only at very low concentrations. Volatilization is not significant after release of lubricating oil basestocks to the environment due to the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process. Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities to fish, Daphnia, Ceriodaphnia and algal species are above 1000 mg/I using either water accommodated fractions or oil in water dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that acute toxicity would not be observed with these substances due to low water solubility. Results from chronic toxicity tests show that the no observed effect level (NOEL) usually exceeds 1000 mg/I for lubricant base oils with the overall weight of experimental evidence leading to the conclusion that lubricant base oils do not cause chronic toxicity to fish and invertebrates. Large volumes spills of lubricant base oils into water will produce a layer of undissolved oil on the water surface that will cause direct physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments. Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch. Extensive experience from laboratory and field trials in a wide range of crops has confirmed that little or no damage is produced as a result of either aerosoi exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%. 13. DISPOSAL CONSIDERATIONS This material under most intended uses would become used oil due to contamination by physical or chemical impurities. RECYCLE ALL USED OIL. While being recycled, used oil is regulated by 40 CFR 279. Use resulting in chemical or physical change or contamination may also subject it to regulation as hazardous waste. Under federal regulations, used oil is a solid waste managed under 40 CFR 279. However, in Califomia, used oil is managed as hazardous waste until tested to show it is not hazardous. Consult state and local regulations regarding the proper handling of used oil. In the case of used oil, the intent to discard it may cause the used oil to be regulated as hazardous waste. Contents should be completely used and containers emptied prior to discard. Rinsate may be considered a RCRA hazardous waste and must be disposed of with care and in compliance with federal, state and local regulations. Large empty containers, such as drums, should be returned to the distributor or a drum reconditioner. To assure proper disposal of small empty containers, consult with state and local regulations and disposal authorities. 14. TRANSPORTATION INFORMATION U S Department of Trans~ortation (DOT~ Shipping Description: Not regulated Note: Material is unregulated unless shipped by land in a packaging having a capacity of 3,500 gallons or more. Then the provisions of 49 CFR, Part 130 apply. International Maritime Dangerous Goods (IMDG~ Shipping Description: Not regulated International Civil Aviation Org / International Air Transport Assoc (ICAO/IATA~ Shipping Description: Not regulated 15. REGULATORY INFORMATION U.S. Regulations: CERCLA/SARA - Section 311/312 (Title III Hazard Cateaoriesl Acute Health: Yes Chronic Health: No MSDS Code: 778846 StBtus: Final Page 7!7 Date of Issue: 31-Aug-2006 Fire Hazard: No Pressure.Hazard: No Reactive Hazard: No CERCLAISARA - Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372: -None Known-- , EPA ICERCLA) Reportable Quantitv lin ooundsL -None Known-- CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs {in poundsL This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372: - None Known - California Prouosition 65: Warning: This material may contain the following chemicals which are known to the State of Califomia to cause cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health 8~ Safety Code Section 25249.5): - None Known - Carcinogen Identification: This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for carcinogenicity information of individual components, if any. TSCA: All components are listed on the TSCA inventory. International Regulations: Canadian Requlations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Domestic Substances List: Listed WHMIS Hazard Class: Not Regulated U.S. Export Control Classification Number: EAR99 16. OTHER INFORMATION Issue Date: 31-Aug-2006 Previous Issue Date: None Product Code: 1052762 Revised Sections or Basis for Revision: New MSDS MSDS Code: 778846 Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. MSDS Code: 721780 Status: Final ~~ iA'~~~~ Page 1/7 Date of Issue: 17-Jun-2005 MATERIAL SAFETY DATA SHEET 76 Super Motor Oil (All Gradesj 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: 76 Super Motor Oil (All Grades) Product Code: 1043286, 1043331, 1043376, 1043401 Synonyms: 76 Super Motor Oil, SAE 10W-40 76 Super Motor Oil, SAE 20W-50 76 Super Motor Oil, SAE 30 76 Super Motor Oil, SAE 40 Intended Use: Crankcase Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-435-7761 EMERGENCY OVERVIEW 24 Hour Emergency Telephone Numbers: Spi.ll, Leak, Fire or Accident Call CHEMTREC: North America: (800) 424-9300 Others: (703) 527-3887 (collect) California Poison Control System: (800) 356-3219 Heaith Hazards/Precautionary Measures: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Physical Hazards/Precautionary Measures: Keep away from all sources of ignition. Appearance: Physical Form: Odor: NFPA 704 Hazard Class: Health: Flammability: Instability: Amber Liquid Characteristic petroleum 1 (Slight) 1 (Slight) 0 (Least) 2. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Com onent / CAS No: Percent % ACGIH: OSHA: NIOSH: Other: inc Compound(s) PROPRIETARY 0.5-1.5 NE NE NE NE MSDS Code: 721780 Status: Final Page 2/7 Date of Issue: 17-Jun-2005 NON-HAZARDOUS COMPONEN TS Com onent / CAS No: Percent % ACGIH: OSHA: NIOSH: Other: Lubricant Base Oil (Petroleum) 76-91 Smg/m3 TWA 5 mg/m3 TWA 2500 mg/m3 IDLH as Oil Mist, if ARIOUS 10 mg/m3 STEL Generated 5 mg/m3 NOHSC TWA dditives 9-24 NE NE NE NE PROPRIETARY The base oil for this product can be a mixture of any of the following highly refined petroleum streams: CAS 64741-88-4; CAS 64741- 89-5; CAS 64741-96-4; CAS 64741-97-5; CAS 64742-01-4; CAS 64742-52-5; CAS 64742-53-6; CAS 64742-54-7; CAS 64742-55-8; CAS 64742-56-9; CAS 64742-57-0; CAS 64742-62-7; CAS 64742-63-8; CAS 64742-65-0; CAS 72623-83-7; CAS 72623-85-9; CAS 72623-86-0; CAS 72623-87-1 Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. 1 %=10,000 PPM. NE=Not Established 3. HAZARDS IDENTIFICATION Potential Health Effects: Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation (Breathing): No information available. Studies by other exposure routes suggest a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include nausea, diarrhea, irritation of the digestive tract, irritation of the nose and throat. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Cancer: Inadequate evidence available to evaluate the cancer hazard of this material. See Section 11 for carcinogenicity information of individual components, if any. Target Organs: No data available for this material. Developmental: No data available for this material. Other Comments: None Known Pre-Existing Medical Conditions: None known. 4. FIRST AID MEASURES Eye: If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Wipe material from skin and remove contaminated shoes and clothing. Cleanse affected area(s) thoroughly by washing with mild soap and water and, if necessary, a waterless skin cleanser. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing~: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. If victim is not breathing, ciear airway and immediately begin artifcial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. \ 1 MSDS Code: 721780 Status: Final ~ Page 3/7 Date of Issue: 17-Jun-2005 Notes to Physician: High-pressure hydrocarbon injection injuries may produce substantial necrosis of underlying tissue despite an innocuous appearing external wound. Often these injuries require extensive emergency surgical debridement and all injuries should be evaluated by a specialist in order to assess the extent of injury. Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. 5. FIRE-FIGHTING MEASURES Flammable Prooerties: Fiash Point: OSHA Flammability Class: LEL%: UEL%: Autoignition Temperature; 365°F / 185°C (PMCC) (minimum) Not applicable No data No data No data Unusual Fire 8~ Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant (see Section 8). Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). MSDS Code: 721780 Status: Final 7. HANDLING AND STORAGE Page 4/7 Date of Issue: 17-Jun-2005 Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Sections 2 and 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empry" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. High pressure injection of hydrocarbon fuels, hydraulic oils or greases under the skin may have serious consequences even though no symptoms or injury may be apparent. This can happen accidentally when using high pressure equipment such as high pressure grease guns, fuel injection apparatus or from pinhole leaks in tubing of high pressure hydraulic oil equipment. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Storage temperatures above 113°F inay lead to thermal decomposition, resu~ting in the generation of hydrogen sulfide and other sulfur containing gases. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. 8. EXPOSURE CONTROLS / PERSONAL PR07CECTION Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits (see Section 2), additional engineering controls may be required. Personal Protective Equipment (PPE): Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits (see Section 2). Protection provided by air purifying respirators is limited (see manufacturers respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). ' Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 9. PHYSICAL AND CHEMICAL PROPERTIES Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Appearance: Amber Physical Form: Liquid MSDS Code: 721780 Status: Final Page 5/7 Date of Issue: 17-Jun-2005 Odor: Odor Threshold: pH: Vapor Pressure (mm Hg): Vapor Density (air-1): Boiling Point: Solubility in Water: Partltion Coe~cient (n-octanol/water) (Kow): Specific Gravity: Bulk Density: Viscosity cSt @ 100°C: Viscosity cSt @ 40°C: Percent Volatile: Evaporation Rate (nBuAc=1): Flash Point: LEL%: UEL%: Autoignition Temperature: Decomposition Temperature: 10. STABILITY AND REACTIVITY Characteristic petroleum No data Not applicable <1 >1 No data Negligible No data 0.86-0.89 7.16-7.41 15.1 - 21.4 88 - 202 Negligible <1 365°F / 185°C (PMCC) (minimum) No data No data No data No data Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidizing agents, strong reducing agents. Hazardous Decomposition Products: Combustion can yield carbon, nitrogen, sulfur, phosphorus, and zinc oxides. Hydrogen sulfide may also be released. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Chronic Data: Lubricant Base Oil (Petroleum) - CAS: VARIOUS Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and dewaxing to remove aromatics and improve performance characteristics. All of the oils meet the IP-346 criteria of less than 3 percent PAH's and therefore none are listed as a carcinogen by NTP, IARC, or OSHA. Acute Data: Additives - CAS: PROPRIETARY Derma/ LD50 = No information available LC50 = No information available Oral LD50 = No information available Zinc Compound(s) - CAS: PROPRIETARY Dermal LD50 = No information available LC50 = No information available Ora/ LD50 = No information available Lubricant Base Oil (Petroleum) - CAS: VARIOUS Derma/ LD50 = >2 g/kg LC50 = No information available Oral LD50 = >5 g/kg MSDS Code: 721780 Status: Final Page 6/7 Date of Issue: 17-Jun-2005 12. ECOLOGICAL INFORMA~CION Not evaluated at this time. 13. DISPOSAL CONSIDERATIONS This material under most intended uses would become used oil due to contamination by physical or chemical impurities. RECYCLE ALL USED OIL. While being recycled, used oil is regulated by 40 CFR 279. Use resulting in chemical or physical change or contamination may also subject it to regulation as hazardous waste. Under federal regulations, used oil is a solid waste managed under 40 CFR 279. However, in California, used oil is managed as hazardous waste until tested to show it is not hazardous. Consult state and local regulations regarding the proper handling of used oil. In the case of used oil, the intent to discard it may cause the used oil to be regulated as hazardous waste. Contents should be completely used and containers emptied prior to discard. Rinsate may be considered a RCRA hazardous waste and must be disposed of with care and in compliance with federal, state and local regulations. Large empty containers, such as drums, should be returned to the distributor or a drum reconditioner. To assure proper disposal of small empty containers, consult with state and local regulations and disposal authorities. 14. TRANSPORTATION INFORMATION DOT Proper Shipping Description: Not Regulated Note: Material is unregulated unless in container of 3500 gallons or more, then provisions of 49 CFR Part 130 apply for land shipment. 15. REGULATORY INFORMATION U.S. Regulations: EPA SARA 311/312 (Title III Hazard Cateaories Acute Health: Yes Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No SARA - Section 313 and 40 CFR 372: This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372: Zinc Compound(s) ................PROPRIETARY................0.5-1.5% EPA (CERCLA) Reportable Quantity (in pounds~ --None Known-- CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQ~in pounds~ This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372: -- None Known -- California Pro~osition 65• Warning: This material contains the foilowing chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Used engine oils, while not a component of this material, is on the Proposition 65 list of chemicals known to the State of California to cause cancer. Carcinogen Identification• ~ / MSDS Code: 721780 Status: Final Page 7/7 Date of Issue: 17-Jun-2005 This material has not been identified as a carcinogen by NTP, IARC, or OSHA. See Section 11 for carcinogenicity information of individual components, if any. Used motor oil has been identified as a possible skin carcinogen by IARC. TSCA: All components are listed on the TSCA inventory. 16. OTHER INFORMATION Issue Date: Previous Issue Date: Product Code: Revised Sections or Basis for Revision: Previous Product Code: MSDS Code: 17-Jun-2005 3/27/2002 1043286,1043331,1043376,1043401 Physical Properties (Section 9) 3310052000 721780 Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resutting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. ~l MSDS Code: 720740 Status: Final ~ . ' ~~~ Page 1/8 Date of Issue: 05-Oct-2o04 MATERIAL SAFETY DATA SHEET 76 Pitstop Antifreeze/Coolant Concentrate 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Intended Use: Chemical Family: Responsible Party: Customer Service: Technical Information: 76 Pitstop Antifreeze/Coolant Concentrate Antifreeze/Coolant Glycol 76 Lubricants A Division of ConocoPhillips 600 N. Dairy Ashford Houston, Texas 77079-1175 888-766-7676 800-435-7761 The intended use of this product is indicated above. If any additional use is known, please contact us at the Technical Information number listed. EMERGENCY OVERVIEW 24 Hour Emergency Telephone Numbers: Spill, Leak, Fire or Accident Call CHEMTREC: North America: (800) 424-9300 Others: (703) 527-3887 (collect) California Poison Control System: (800) 356-3219 Health Hazards/Precautionary Measures: Overexposure may cause damage to the kidneys, liver. Avoid exposure during pregnancy. Probable birth defect hazard based on animal data. May be harmful or fatal if swallowed. Poisonous to animals. Causes eye irritation. Use ventilation adequate to keep exposure below recommended limits, if any. Do not breathe vapor or mist. Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Wash thoroughly after handling. Physical Hazards/Precautionary Measures: Keep away from all sources of ignition. Appearance: Green Physical Form: Liquid Odor: Mild glycol NFPA 704 Hazard Class: HMIS Hazard Class: Health: 1 (Slight) Health: 2' (Moderate) Flammability: 1 (Slight) Flammability: 1 (Slight) Instability: 0(Least) Physical Hazards: 0(Least) ' Indicates possible chronic health effects. MSDS Code: 720740 StatuS: Final Page 218 Date of Issue: 05-Oct-2004 2. COMPOSITION / INFORMATION ON INGREDIENTS HAZARDOUS COMPONENTS Com onent / CAS No: Percent % ACGIH: OSHA: NIOSH: Other: Diethylene Glycol 111-46-6 0-5 NE NE NE NE Dipotassium Phosphate 7758-11-4 1-2 NE NE NE NE Ethylene Glycol 107-21-1 90-95 100 mg/m3 CEIL Aerosol NE NE NE All components are listed on the TSCA inventory. Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. 1 %=10,000 PPM. NE=Not Established 3. HAZARDS IDENTIFICATION Potential Health Effects: Eye: Eye irritant. Contact may cause stinging, watering, redness, and swelling. Skin: Contact may cause mild skin irritation including redness, and a burning sensation. Prolonged or repeated contact can worsen irritation by causing drying and cracking of the skin leading to dermatitis (inflammation). Contact may result in skin absorption but symptoms of toxicity are not anticipated by this route alone under normal conditions of use. Inhalation (Breathing): No information available on acute toxicity. See signs and symptoms. Ingestion (Swallowing): Toxic. May be harmful if swallowed. Signs and Symptoms: Effects of overexposure may include irritation of the nose and throat, irritation of the digestive tract, coughing, nausea, vomiting, diaRhea, abdominal pain, muscle contractions, irregular heartbeats (arrhythmias), hypotension (low blood pressure), pulmonary edema (accumulation of fluids in the lungs), visual disturbances, transient excitation followed by signs of nervous system depression (e.g., headache, drowsiness, dizziness, loss of coordination, disorientation and fatigue)., convulsions, coma. Cancer: Inadequate data available to evaluate the cancer hazard of this material. Target Organs: Overexposure may cause injury to the kidney. Animal studies have shown that overexposure may cause injury to the liver, (see Section 11). Developmental: Potential hazard to the fetus (see Section 11). Other Comments: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage (sometimes referred to as Solvent or Painters' Syndrome). Intentional misuse by deliberately concentrating and inhaling this material may be harmful or fatal. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders, respiratory (asthma-like) disorders, kidney disorders, liver disorders. ~ } MSDS Code: 720740 Status: Final 4. FIRST AID MEASURES Page 3l8 Date of Issue: o5-Oct-2004 Eye: Move victim away from exposure and into fresh air. If irritation or redness develops, flush eyes with clean water and seek medical attention. For direct contact, hold eyelids apart and flush the affected eye(s) with clean water for at least 15 minutes. Seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water. If irntation or redness develops and persists, seek medical attention. Inhalation (Breathing): If respiratory symptoms or other symptoms of exposure develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek immediate medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention. Ingestion (Swallowing): If swallowed, seek emergency medical attention. If victim is drowsy or unconscious and vomiting, place on the left side with the head down and do not give anything by mouth. If victim is conscious and alert and ingestion occured within the last hour, vomiting should be induced for ingestions of more than 1 swallow (1-2 tablespoons for an adutt) preferably under direction from a physician or poison center. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Notes to Physician: This material contains ethylene glycol. Toxic metabolites of this material may cause acidosis, coma, convulsions, renal failure, or circulatory collapse. Ethanol blocks the formation of glycolic acid and therefore is the antidote of choice. Because of the rapid conversion (3-hour elimination half-life) of the ethylene glycol, ethanol should be administered as soon as possible in cases of severe poisoning. If inedical care will be delayed several hours, use 3-4 one-ounce oral (shots) of 86-proof whiskey before or during transport to the hospital. The use of intravenous ethanol and hemodialysis effectively removes ethylene glycol and glycolic acid from the body. Case studies or animal experiments suggest that a component of this material may produce acute tubular necrosis following an overdose. The monitoring of urine output, serum creatinine, electrolytes, acid base balance, urine hemoglobin, and serum calcium is recommended following significant exposure. The use of intravenous ethanol and hemodialysis may be considered following serious poisoning because of their effectiveness in ethylene glycol toxicity. However, the effectiveness of these treatment modalities with other glycols is not well established. 5. FIRE-FIGHTING MEASURES Flammable Properties: Flash Point: 250°F / 121 °C(COC) OSHA Flammability Class: Not applicable LEL%: 3.2 UEL%: 15.3 Autoignition Temperature: No data Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. Vapors are heavier than air and can accumulate in low areas. If container•is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical liazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be wom. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. 6. ACCIDENTAL RELEASE MEASURES .l ; MSDS Code: 720740 Status: Final Page 418 Date of Issue: 05-Oct-2004 This material may burn, but will not ignite readily: Keep all sources of ignition away from spilllrelease. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment including respiratory protection as conditions warrant (see Section 8). Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. 7. HANDLING AND STORAGE Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Sections 2 and 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits (see Section 2), additional engineering controls may be required. Personal Protective Equipment (PPE): Respiratory: A NIOSH certified air purifying respirator with an organic vapor cartridge (add a Type 95 (R or P) particulate prefilter for particulates) may be used under conditions where airborne concentrations are expected to exceed exposure limits (see Section 2). Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a positive pressure air supplied respirator if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection.A respiratory protection program that meets OSHA's 29 CFR 1 J10.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact, possible irritation, and skin damage. Examples of approved materials are polyethylene, neoprene, nitrile, polyvinyl alcohol, natural rubber, or butyl rubber (see glove manufacturer literature for information on permeability). Depending on conditions of use, apron and/or arm covers may be necessary. Eye/Face: The use of a face shield and chemical goggies to safeguard against potential eye contact, irritation, or injury is recommended. Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse. It is recommended that impervious clothing be worn when skin contact is possible. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 9. PHYSICAL AND CHEMICAL PROPERTIES Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). ~ MSDS Code: 720740 Status: Finai Page 5/8 Date of Issue: o5-Oct-2oo4 Appearance: Physical Form: Odor: Odor Threshold: pH: Vapor Pressure (mm Hg): Vapor Density (air-1): Boiling Point: Melting/Freezing Point: Solubility in Water: Partltion Coefficient (n-octanol/water): Specific Gravity: Bulk Density: Bulk Density Units VOC Content(%): Percent Volatile: Evaporation Rate (nBuAc=1): Flash Point: Test Method: LEL%: UEL%: Autoignition Temperature: 10. STABId.ITY AND REACTIVITY Green Liquid Mild glycol No data 10.5-11.0 (50% water solution) < 0.1 2.1 339-348°F / 171-175°C 0°F / -18°C Complete -1.36 1.12 9.3 Ibs/gal 1113 g/I 97% Nil 250°F/121°C (COC) 3.2 15.3 No data Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Heat, sparks, flame. Materials to Avoid (Incompatible Materials): Avoid contact with strong acids, strong oxidizing agents. Hazardous Decomposition Products: Combustion can yield carbon dioxide, carbon monoxide. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Ghronic Data: Diethylene Glycol - CAS: 111-46-6 Target Organs: Accidental human ingestion of diethylene glycol resulted in kidney damage (severe renal epithelial damage, tubular necrosis, and anuria). Liver damage (vacuolation and hyaline degeneration) was also seen in rats fed diets containing 1 to 4% diethylene glycol for 2 years. Ethylene Glycol - CAS: 107-21-1 Target Organs: Ingestion of ethylene glycol by humans results in kidney damage (renal epithelial damage and oxalate crystals in the tubules). Administration of ethylene glycol resulted in hepatocellular hyaline degeneration in male mice fed diets containing 12,500 or 25,000 ppm ethylene glycol and female mice fed diets containing 50,000 ppm ethylene glycol. Deve/opmental: Ethylene glycol caused malformations in the offspring of mice and rats when administered by gavage or in the drinking water during organogenesis. It was not teratogenic when fed in the diet, by dermal application of up to 3550 mg/kg/day or by nose-only inhalation at up to 2500 mg/m3. No effects on fertility or reproductive performance were seen in a three- generation study in rats exposed orally. Acute Data: Diethylene Glycol - CAS: 111-46-6 Dermal LD50 = No information available LC50 = No information available Oral LD50 =13.3 g/kg (rabbit); 11.9 g/kg (rabbit) l MSDS Code: 720740 StBtus: Finai Dipotassium Phosphate - CAS: 7758-11-4 Dermal LD50 = No information available LC50 = No information available Oral LD50 = No information available Ethylene Glycol - CAS: 107-21-1 Dermal LD50 = = 9,530 mg/kg(rabbit) LC50 = >200 mg/m3/2h (mice); = 10.9 mg/I (rat) Oral LD50 == 1.5 g/kg (est. human) 12. ECOLOGICAL INFORMATION Toxiciry to Micro-organisms: Bacterial / NA: 16hr; IC50 Result Value: >100,000 mg/I Toxicity to Aquatic Invertebrates: Daphnia: 48hr; LC50 Result Value: >1000,000 mg/I Toxicity to Fish: Fathead Minnow: 94hr; LC50 Result Value: 70,000 mg/I BOD (% Oxgen Consumption): Day5=51% Day 10 = 80% Day 20 = 97% Chemical Oxyten Demand (COD) - Measured: 1.29 mg/mg Theoretical Oxygen Demand (ThOD) - Calculated: 1.30 mg/mg 13. DISPOSAL CONSIDERATIONS DO NOT discharge into sewer. Page 6/8 Date of Issue: o5-Oct-20o4 This material, if discarded as produced, is not a RCRA "listed" hazardous waste. However, it should be fully characterized for toxicity prior to disposal (40 CFR 261). Use which results in chemical or physical change or contamination may subject it to regulation as a hazardous waste. Along with properly characterizing all waste materials, consult state and local regulations regarding the proper disposal of this material. Container contents should be completely used and containers should be emptied prior to discard. Container rinsate could be considered a RCRA hazardous waste and must be disposed of with care and in full compliance with federal, state and local regulations. Larger empty containers, such as drums, should be returned to the distributor or to a drum reconditioner. To assure proper disposal of smaller empty containers, consult with state and local regulations and disposal authorities. ~1 ~ MSDS Code: 720740 Status: Final Page 718 Date of Issue: OS-Oct-20o4 14. TRANSPORTATION INFORMATION DOT Proper Shipping Name: Environmentally hazardous substances, liquid, n.o.s. (Ethylene Glycol) Hazard Class/Division: 9 UN Code: NA3082 Packing group: III RQ' Bulk Package/Placard Marking: Class 9/3082 Non-Bulk Package Marking: None Non-Bulk Package Labels: None Hazardous Substance: Ethylene Glycoll5,000 Ib. Emergency Response Guide: 171 Note: This product is unregulated by DOT when shipped in non-bulk quantities. IMDG Shipping Description: Not regulated (in quantities under 5,000 Ibs in any one inner package) ICAO/IATA Shipping Description: Not regulated 15. RE GULATORY INFORMATION U.S. Regulations: PA SARA 311/312 (Title III Hazard Cateaories Acute Health: Yes Chronic Health: Yes Fire Hazard: No Pressure Hazard: No Reactive Hazard: No S~RA - Section 313 and 40 CFR 372• This material contains the following chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372: Ethylene Glycol ................107-21-1................90-95% EPA (CERCLA) Reportable Quantity (in pounds~ Ethylene Glycol ................107-21-1................5000 CERCLAISARA - Section 302 Extremely Hazardous Substances and TP~s (in pounds1 This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372: -- None Known -- California Proposition 65: Waming: This material contains the following chemicals which are known to the State of Calfomia to cause cancer, birth defects or other reproductive harm, and are subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): -- None Known -- Carcinogen Identification: This material has not been identified as a carcinogen by NTP, IARC, or OSHA. TSCA: All components are listed on the TSCA inventory. International Regulations: Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Domestic Substances List: Listed WHMIS Classification: D2A-Materials causing other toxic effects - Very Toxic Material . MSDS Code: 720740 Status: Final Page 8l8 Date of Issue: 05-Oct-2o04 International Inventories: One or more components are listed on the following inventories: Australia (AICS) Canada(DSL) China Europe (EINECS) Korea (Existing and Evaluated Chemical Substances) Philippines (PICCS) 16. OTHER INFORMATION Issue Date: 05-Oct-2004 Previous Issue Date: 01/01/2002 Reason for revision: Changed responsible party from Phillips to ConocoPhillips. Other formatting changes Composition information modified - SEE SECTION 2 MSDS Code: 720740 Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are fumished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. ~ PHIUIPS ~ ~6 Triton Synthetic Gear Lube (All ° ' ~~~°C° Grades) Material Safety Data Sheet ., 1;~x£~i,PRODUCT~AND,~COMPANYxIDENT#FiC%ATION~y~~~~~ . ' ; ~,~~~~~,~~~,~~~~~~~~~~~~~~~.`~ ~ ~~~ ~ Product Name: Triton Synthetic Gear Lube (All Grades) MSDS Code: 778906 Synonyms: Triton Synthetic Gear Lube, SAE 75W-90 Triton Synthetic Gear Lube, SAE 80W-140 Intended Use: Automotive Gear Lubricant Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Infortnation: 800-255-9556 MSDS Information: Intemet: http://w3.conocophillips.com/NetMSDS/ Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours) California Poison Control System: 800-356-3219 Emergency Overview NFPA This material is not considered hazardous according to OSHA criteria. a~ . Appearance: Amber Physical Form: Liquid Odor: Characteristic petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness and a burning sensation. No harmful effects from skin absorption are expected. Inhalation (Breathing): Expected to have a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects reported from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: None Known See Section 11 for additional Toxicity Information. 3~~~C`OMPOS'ITIO ,N~/~INFt~RMA~T10N~t~N~iNGREDIENTS ~~ ~~~'„# .~~ '~~~~~~~z,~~~. £ ~,` .~... a . ~~s ~,'.,~. ~~x~..." ~`~ .~:,~~~:~~~ 778906 - Triton Synthetic Gear Lube (All Grades) Page 1/6 Date of Issue: 12-Apr-2007 Status: Final 778906 - Triton Synthetic Gear Lube (All Grades) Date of Issue: 12-Apr-2007 Page 2/6 Status: Final 3~C+~MPtJSIT10N~lXINF(3~R~V1~?-T1 Com oiie~t.~~ `~:~~{ .,.~~~;~' a ~.z.` ~ ~~`~~~~ , ,. QNF~4N~INGREDIENTS; ~ ~~~x ~ ~, ~ ~ :~~~ ~ ~ ~~AS ~ ~' ~~r ~' x ,,.F .< ~ _ , ,.a~ ,~ ~~-~'~'°~'~~, ~' ~ `~ ~~ ~ y ~~~~~~~ ~€ ~ ~. ,~. .~,~w ~ ~`~~- , ~~ ~ ~~:~Ccinceiitratioi~~ wt.% °~~; ~.a ~ .~;: S nthetic Lubricant Base Oil PROPRIETARY 25 - 80 dditives PROPRIETARY 20 - 75 .} ~' ~ ,~~( , ^,n. ;y r .'~,"--. b ~~' s.~'~$ ~ k-~e~'_ s ~ ~ ~t' ~. ,t` ' F ~, 9 . ~ -~- €,q ~^,-w°-: ~ t ~ t ~ a "s€ ~'a 3 ~..; w~~~~`k~ lY~~~~ `~a,.a~.>~i a.,.~:,..~'y..~` .'aa~5.~~:'~`"~.n~~~a~~s~t~t~~; ;. ~ ?~ i~.t~~.,'~ ~z-~~~~~ M,~.a'~ ~.>~~„~;.`~y~-~. `~'~':'~ Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure and into fresh air. Seek immediate medical attention. - Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. S~FIRE~~IC .H~I~IG~~11fEASl$1~E~~~~~ ~~~..~ ~,~ ` ~ ,a ~~~~~~ ~ r ~ ~ ~~~~ ~~. ~~~~~~,~: .'r~~~ ~~~. ~~::~~~ `~ . ~ ~ ~_.~ ._,,... `~ ~. ~ ~,~ ~_ .~ NFPA 704 Hazard Class Health: 1 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe) Unusual Fire 8~ Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Vapors are heavier than air and can accumulate in low areas. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits . s~~~~ACCIDENTAL,aRE~EA$E ME~Si1RfS.. ,.~, ~._ ~'~~~~~_, x,~ `E~,,.~ ; ..~r...z..:~~'~~.~~'.:~~~~ _. v~,~;~"~~, Z~~ ..~~ Personal precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Spill precautions: Stay upwind and away from spill/release: Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). Environmental precautions: Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. Methods for cleaning up: Immediate cleanup of any spill is recommended. Notify fire authorities and appropriate federal, state, and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). l 778906 - Triton Synthetic Gear Lube (All Grades) Date of Issue: 12-Apr-2007 Page 3/6 Status: Final . ~,.~1 , ~ .~ . ., ~ ~ ~ 4'~aa ~r.~r %~`,~ s ~~,~c" <nas,~ "x a :~ '"~~..-~ s ati 'SS a~ £~ ~,. ,aHANDLING~AND STOR7AG'E~ ~ }~ ~~~~ ~; ~ ~ ~ ~~ ~ '~` ~`~ ~ ~ ..~ ~:~ ~~ ~~~ . ~~` ~-~ ~~~:~ ~,~. ~~~~~~, ~ti-~,~~.~~~'~~~~~'~'~~~~:~~ Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Section 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. 8 SjEXI?OS.UI~E~CONTROL` S~/ PE~SONAX~§~PRO~EC-~T~IC3N~~~~ ~~~ ~ ~ ~~~~ ~-~h`~~v Y~ ~~~~~ ~' ~~ ~ k~ ~a . ..... ~ . . . __.. ~.~_~ ~ _ .__ ~. ~. ._ . ,. . ~'~~w~~ , ~~~ ~~,. ~-~h•~~~, ;~~~~~,° ..~~,. ~~ ~~ r~,~~;;~~Coim,.~onent,~~.'~~~ r`x~ f~x~~'~~~AiC:GIH~~~ ' ~3,~~,.~:.,..a ~~~~~; ~ ~ ~ ~. ~~ ~ ~ ~ ~~...~~.~,OSHA<~,~'~~.~ ~~ ~ ,~ ~~ ~ '".~,~,_`~ ~ ~~;#~«'?~~:'4..f'~"r~~ther,,a;~~~,a~~ Synthetic Lubricant Base Oil 5mg/m3 TWA 5 mg/m3 TWA -- 10 mg/m' STEL as Oil Mist, if Generated as Oil Mist, if Generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airbome concentrations below the established exposure limits additional engineering controls may be required. Personal Protective Equipment (PPE): Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled, such as nitrile, is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Other Protective Equipment: A source of clean water should be available in the work area for.flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. 9: PHYSICAL~AND;yCHEIVIICA_L~~PRO,'PERTIES. ~,~:d~~~'.~ : ,~a~~~~~~~ R,~~~~w;«`.k~ ,~~~~~~~~v,~~r~~~`~~x~~" ~~~'~~-~. .~~.~ Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). ~ 778906 - Triton Synthetic Gear Lube (All Grades) Date of Issue: 12-Apr-2007 Page 4/6 Status: Final Appearance: Physical Form: Odor: Odor Threshold: pH: Vapor Pressure: Vapor Density (air-1): Boiling Point/Range: Melting/Freezing Point: Partition Coefficient (n-octanollwater) (Kow): Speciflc Gravity: Bulk Density: Viscosity: Evaporation Rate (nBuAc=1): Flash Point: Test Method: LEL (vol °/, in air): UEL (vol % in air): Autoignition Temperature: Amber Liquid Characteristic petroleum No data Not applicable <1 >1 No data No data No data 0.89 - 0.91 @ 60°F (15.6°C) 7.41 - 7.58 Ibs/gal 15.0 - 32.0 cSt @ 100°C; 116 - 298 cSt @ 40°C No data Minimum 338°F / 170°C Cleveland Open Cup (COC), ASTM D92 No data No data No data 9 r ~ `~ r '~4 "` " <'~ ~ - ~ - d ,„d;.;~r`er~s~~ ~r~ aat .~,,.,~,,,`. ,~ ~, . 10 ~~S~TABIL~ITI(~AND~~REACTii/1T~1(:~~,~,~.~~~;~v ~, k '~ ~ ` ~ ~ ~m ~~~~ ~~~~ ~ ~~s~~ ~~~ ;~. Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials): Avoid contact with strong acids, strong bases and strong oxidizing agents. Hazardous Decomposition Products: Combustion can yield oxides of carbon, nitrogen, sulfur and phosphorus. Hazardous Polymerization: Will not occur. y, 1~1~~TOXiCO~LOGIC~I1L~~tNFURMA~TIO~N~~`~~`` °~ ~"~ ~`~` ~ `~'~` ~~ ` '~ r ... . ,.. .. ....,. , .. ,.... .. .< .., ,. . .. ......?'w ~E-ii~;~~......~ ~~ ,.~`.M.''i,~. ~us?w;~~ss.s a , . t.`r, +,.~- . .~r ..k~.~~A~»~-"'~1.: '~,33,. •.,.~L' ::~~v'".&~,~t~,d~g'~ . Acute Data: Not evaluated. 1~3 ', DISPOSAL~~CQNSIDERATIONS g~ ~~~~.~.~:~ ~'~~ ~~~~~~~`~~'~~~,,~2~~'~~ ~~~~~ ~r~~,~~~ a~~,.~`~n ~~~;~~.~~~~~~~~~~~ The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities.. Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. 1:2 ~~ECOLOGICAL;>INF~ORMATIONs~~~~~..~: ~}. ~~,R~ . ~~~~~~~"~,~5 °~~~~~;~~ '~'~~~~~~~a~~~~~ ~~~~~ ~~'... 778906 - Triton Synthetic Gear Lube (All Grades) Date of Issue: 12-Apr-2007 Page 5/6 Status: Final . rye 1'4 TRANSPt7RT~ATION°INFORMATION~~~~~~ ~~`~~~,~~~~~~~ ~ _ ° ~~~~~$ ,,,.~ ~~~_~~~~~~~~~ ~ ~ . ., .. ~ 1 ~ . , ~ ~: ~ ~ ~ ~~~ ~ ~ _ _,. z.,,r a ~. _.~ ~ _ - - -°~~ ..,, ., h. _ r. ~~~c~t~;~..; ~ ~~,~.<;~ ~ u~.,~~.~r. ~~'~..°~~ . bz~ ~ ~~~ ~~, ~~.~, _°°~s ~,~s.~ U.S. Department of Transportation (pOT~ Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) International Maritime Dangerous Goods (IMDG~ Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. Intemational Civil Aviation Org. / International Air Transport Assoc (ICAO/IATA~ UN/ID #: Not regulated Note: 'Additional Federal compliance requirements may apply. See 49 CFR 171.11. LTD. QTY Passenger Aircraft Cargo Aircraft Only Packa in Instruction #: ~- - __ ~ Max. Net Q. Per Packa e: ~ - ~ ~ ; , `~vw ~ .'~ Y "" " C' # ~ "+°. ~ ;~' S^r+ .* s ~"~w ~ ' .> i ~. .:.~ ~ o ~z' ~ a<x-'te 1;5~REGULAT~ORY~INF,4RNIA~TION~~~~. . ~ ~ ,.. ~~~.°~~~~~`~~~~.,~`.~,-~~,~ ~~.~ ~ ~~~~~~n~ ~~ ~~~~ti =.~~,~~~~~ CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in poundsl• This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/372 (Title III Hazard Cateaories Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLA/SARA - Section 313 and 40 CFR 372• This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA (CERCLA) Reportable Quantit~(in pounds)• This material contains the following chemicals subject to the reporting requirements: California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): ~ ~ ~ ~ ~ ~. .~ ~ ~rw ~ ~~~v'~ .~.~„~,~v..~~~ ~ Com.~vnent.~~ ~z~~~~ ~~x. ..,~~~,f~f ~~ ~~~ ~ ..~ .. ~ ~~ ~ ~ <~ ~'~~.~~~'~~~~~~~~~ ~h~;T e;rif~Tozici w~..~~A&~'.~xY~~~~~~~~~~~~:~ Aniline Cancer Arsenic Inor anic Arsenic Com ounds Cancer ~ Cadmium / Cadmium Compounds Cancer Developmental Toxicant Male Re roductive Toxicant Eth I Ac late Cancer Lead / Lead Compounds Cancer Developmental Toxicant Female Reproductive Toxicant Male Re roductive Toxicant 1-Na hth lamine Cancer 2-Na hth lamine Cancer i 778906 - Triton Synthetic Gear Lube (All Grades) Date of Issue: 12-Apr-2007 Page 6/6 Status: Final Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the inforrnation required by the CPR. WHMIS Hazard Class None National Chemical Inventories: All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. This product contains one or more components on the NDSL (Non-Domestic Substances List) which are subject to Canada's New Substance Notification requirements if exported quantities of component exceed 1000 kg/yr. All other components are on the DSL. U.S. Export Control Classification Number: EAR99 ,„ _ , . r"` `f ~ ~ ~" ~ h ~" au~ ~, ~ s'~s~-'a ~~~ ~a*_`r #``°~,,rr , n"s ~' .~~'~.+.,'+txii' ~''3 ~ ' : §~~~~~e~~~+~'~~~``~~ ~~~ ~ ~ ,yy~. 1r6~O,~THER,xINF!~;RN!/~~TIO-N. ~.._~~~~ ~~~~~ . , v ~~~;, u~~.~; ~ °. ~ :~. ~~~, ~~~ y ~ ~~ Issue Date: 12-Apr-2007 Status: Finai Revised Sections or Basis for Revision: New MSDS MSDS Code: 778906 MSDS Legend: ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service Registry; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; IARC = Intemational Agency for Research on Cancer; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Supertund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. 1 ~ ~~ ~~~~~~ , ; 76 High Perforrr~ance Full Synthetic Motor Oi! (All Grades) Material Safety Data Sheet 1': ,~~PROD,UCaTn~~AN~~COMPANY~IDENTIFIC~A~tlt'3N~`~~~, ~ ~~~~~~~~ ~ ~`~~` ~~`~~ ~' ~~~~. ~ ~~~~~ ~=-~~< ~.~~ s. .. ti~.; { ~.~ ;, ~~ ~ .~:~.,. ~~~~~.,~~~. ~ ~ ~~ Product Name: 76 High Performance Full Synthetic Motor Oil (All Grades) MSDS Code: 722910 Synonyms: 76 High Performance Full Synthetic Motor Oil, SAE 5W-20 76 High Performance Full Synthetic Motor Oil, SAE 5W-30 76 High Performance Full Synthetic Motor Oil, SAE 10W-30 76 High Performance Full Synthetic Motor Oil, SAE 20W-50 Intended Use: Crankcase Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-255-9556 MSDS Information: Intemet: http://w3.conocophillips.com/NetMSDS/ Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours) Califomia Poison Control System: 800-356-3219 _.. .. . HA~ZARD;S~IDENTIFIC~ATION~~~~~'~;+5~~~ ~~ ~s~ y ~~ ~ ~ ~` .~k`~.~~ ~ ~' S ~ £ ~ '~ ~ *~ .t~,,. ~~~'.,.~~~~ . ~,.,~~r ~~...~~'~~`~~ ~ zv~'.~~°~~ S, ~ ~~~'~:~ ,r,°.~`,~~,.~~~:~~a~ z.~Y~ Emeraency Overview NFPA This material is not considered hazardous according to OSHA criteria. 0` Appearance: Amber Physical Form: Liquid Odor: Characteristic petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness and a buming sensation. Prolonged or repeated contact can defat the skin, causing drying and cracking of the skin, and possibly dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation (Breathing): Expected to have a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. See Section 11 for additional Toxicity Information. 722910 - 76 High Performance Full Synthetic Motor Oil (All Grades) Page 116 Date of Issue: 02-Apr-2007 Status: Final \ / 722910 - 76 High Performance Fuli Synthetic Motor Oil (All Grades) Page 2/6 Date of Issue: 02-Apr-2007 Status: Finai -~v~a ~ i ~ T ° ~ .>"y ,~,rY"~~St~.~~r::tr~ kn.c$1"~ ~~x'~~~4+'g ~ ~,~,.. 3 ~ COMPOSITION:}I~INFORMA~TION;ON,.INGREDIENTS~,~' , ~ w.~~~~ ~ ~~.~:.~~ ~ .: . ~~~~~~ ~.3 ~ ~ ~ . .~~~ ~~ S nthetic Lubricant Base Oil PROPRIETARY 74 - 84 dditives PROPRIETARY 16 - 26 ~T(~ r~ , ~ ~~. 3 ,(~~. "` 'k ~, 'r~,~Y~~+ ~~-~~,~ 9 t"S~,"~*M°~ ~ Msr :~.L ~ ~ ~' ~~~3~'x?~~' ~ ~ `"~~ t R '~y~ ;4~ ~°'k r~,. ~r.~~~'.~ ~.' ~tr s<„' b -az .~,a~~ ; '~`~ °i ~c ,a~(r11~J1 ~y~M1L!'1~7~ ^U / s~ ~+8e~" ~ e ' ?~'.~` ^~~~~ ~;. ";~ v~r~ :'~t°.~ ~r ys ~ '* ~a..~" '~~i ~~ ~ ~ ' '. . .. ....~ ., .. , .xs~ .r,ri ,.. ri~.c.~u ..,y, ~...., ,~ ~ a,N,.,+~ . v,brv!~,.~x ~. ~ sa.,- , . ... . . .-S ~ ~.°.~^~'Y~ ,~'~~,~~ , _e _~3~ .. R.4o Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention. Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing): First aid is not normaily required. If breathing difficulties develop, move victim away from source of exposure and into fresh air. Seek immediate medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. .~„~ . r. A < ... ~ F >y.~,- s . ~..~@e~'~9~~2 ne .~iL ~ "'dE y.~ Y ~v.^ k.d4 ~ y - Y $ ~'aY~W'~s; ~~F,IRE,FIG`HTING~MEASURES~y=.~x~,~r~z~~ ~.~~~~.~~, ~'~'`~ ,~~~~~~~~. ~~~Y~a~~~;~~~~~~ ...z~~~~~m;~4.~ NFPA 704 Hazard Class Health: 1 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe) Unusual Fire 8 Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Vapors are heavier than air and can accumulate in low areas. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area, keep unauthorized personnei out. Stop. spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits . ~ ,... ~ c ~ 4 r' ~ '~ ~ 'IT"d,~ '~ v ~,y~Y v *~3e a r~: 6 s AC;CIDENTALsRELE~-SE~MEASURES~ ~~~ r..~ ~~~~~~~~ x~ ~~~~ ~~._~'~,~`~~~.z.~~ ~.~~`~~~.,~ .~,.~e~~~~~`~~ ..::~~~~-~~~~~,~ Personal precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. Spill precautions: Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). Environmental precautions: Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate absorbent material. 722910 - 76 High Performance Full Synthetic Motor Oil (All Grades) Page 3l6 Date of Issue: 02-Apr-2007 Status: Final Methods for cleaning up: Immediate cleanup of any spill is recommended. Notify fire authorities and appropriate federal, state, and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Section 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Used motor oils have been shown to cause skin cancer in mice after repeated application to the skin without washing. Brief or intermittent skin contact with used motor oil is not expected to cause harm if the oil is thoroughly removed by washing with soap and water. Storage: Keep container(s) tightly closed. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Use and store this material in cool, dry, weli-ventilated areas away from heat and all sources of ignition. Storage temperatures above 113°F inay lead to thermal decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. , ,~~ 8: ~.EXPOSU:RE~CONTRO"LS,~/~PERSONAL~P~R°OTECTI`ON~~~~`~~~`~.~~„.~~ . ;~ax,~~ q° .~ ~~~~~~-~ ,~~.~~ . ~ .., ~'~~~,~~"~z„~`;~C.oiit" onent~~ ~~~~ '~ ~`~'~~`~~~ '~z ~ACGIH ~~'~~~~~~~ ,~ ~.< ~~ ~~ ~. ~~ ~~ ~ : ~ ~ ~. ~,~x.. ~ ~, ~~~; .~. ,.:~ u_~, ~OSHA~ g;~.~~~~~.;~ ~ ~ ~ ~~ ~~ ~~~. .~~~~`.~~~Other~~~. ~~~~~~.`,~t~ Synthetic Lubricant Base Oil Smg/m3 TWA 5 mg/m' TWA -- 10 mg/m3 STEL as Oil Mist, if Generated as Oil Mist, if Generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airbome concentrations below the established exposure limits additional engineering controls may be required. Personal Protective Equipment (PPE): Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impenrious to the specific material handled, such as nitrile, is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). Respiratory: A NIOSH certified air_purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited (see manufacturers respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. 722910 - 76 High Performance Fuli Synthetic Motor Oil (All Grades) Date of Issue: 02-Apr-2007 Page 4/6 Status: Final Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin. Impervious clothing should be worn as needed. Suggestions for the use of specific protective materials are based on readily available published data. Users should check with specific manufacturers to confirm the performance of their products. Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Appearance: Physical Fortn: Odor: Odor Threshold: pH: Vapor Pressure: Vapor Density (air-1): Boiling Point/Range: Melting/Freezing Point: Solubility in Water: Partition Coe~cient (n-octanol/water) (Kow): Specific Gravity: Bulk Density: Viscosity: Percent Volatile: Evaporation Rate (nBuAc=1): Flash Point: Test Method: LEL (vol % in air~: UEL (vol % in air): Autoignition Temperature: Amber Liquid Characteristic petroleum No data Not applicable <1 >1 No data No data Negligible No data 0.85 - 0.87 @ 60°F (15.6°C) 7.08 - 7.24 Ibs/gal 8.1 - 21.0 cSt @ 100°C; 43 - 165 cSt @ 40°C Negligible <1 Minimum 365°F / 185°C Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 No data No data No data _ „ .~, . ~. 1~:O~~~ST~AB.IL:IT~Y~,AND,~REACTII/ITY' `'"~ ~~ ~~~°~~~ ~ ~~ ~ ° ~ ~"~`~F ~' ~ ~ ~' `~ ~~~ ._ . _ ~ ~ ~~ ~ x.~:~` ~~~:.~~` ~ . •. ~ .~. . . .. . ' ~~~ , .. ~ a :.~, a~.~ ~a~ ~~~. .~~~, Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials~: Avoid contact with strong oxidizing agents and reducing agents. Hazardous Decomposition Products: Combustion can yield carbon, nitrogen, sulfur, phosphorus, and zinc oxides Hydrogen sulfide and alkyl mercaptans may also be released. During use in engines, contamination of oil with low levels of hazardous combustion products (polycyclic aromatic hydrocarbons) may occur. Hazardous Polymerization: Will not occur. .. '" t .}~. E S~ kY~ Y l~ 'z" Y. "~' y S~ ~ !ti 1~1 ~~TOXICOL'OGICAL""INFflRMi4TION, ~~~~~ .~~`~~~~ ~,'~~ ~~:~~-~K ~~:°;~,~,~~;~;p~~~~,.~. ,~r.~"~~~~~~~~~~~~~,^~~~ ~~~~ This material has not been identified as a carcinogen by NTP, IARC, or OSHA. Acute Data: Synthetic Lubricant Base Oil LD50 (rat) >5,000 mg/kg (similar LD50 (rat) >2,000 mg/kg (similar No data available materiall materiall ~ ~ 3 ~ ~ ~C,~~,s~ ~ » n ~~ a 3 1~~-~2 ECOLQ:GICAL~INFORMATION..;`., '~` ~ ` ~~ ~~ ~~~ ~~~~~`'~ _ ~~~ ~~~~~~~ ~~~ ~ ~ ~~~ ~` .. .. . . _ . . _ ~ "9~. . ~~ ... 4....: ~, 4_ ,a~s..r ~t ~ , . ~ *~ r t, ~~~ ~~ .ti 3 oa a'~.. ~:z~ ''S~ ^~ t i- ~ Not evaluated. ~l 722910 - 76 High Performance Full Synthetic Motor Oil (Ali Grades) Page 5l6 Date of Issue: 02-Apr-2007 Status: Final ~ § r ~ ~ ~ Sk^~y ~. S. X ~ s ^~,~ ~ ~~.t~ ~ ~' ^, ~:. X ~ c~ ~ ~ ~qr a~< ~~ k ~x '~ ~ 1=3, .rDISPOSAL,.~CONSIDERAT1t~NS~~~~~~~°~~~~ .F .. ~, ,~~.~~~ ~ .x . ~ ~~ ~ ~~ ~ , ~. ,- ` ~4~~~ .~~~~ ~ ~ :~ . . ~~.~~~~_ The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. 1'4~~~TRANSP~J„RTAT~~JJ~PI~INFC~i;FtflilA~T~10Ngs~;~~~~.~~~u~~~~~~~~ ~~~~~~.~.~.:.4~~,~~~~~ ~~.. ~~.,~ ..~ ~~~~~~~~,~~ U.S. Department of Transportation (DOT1 Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) International Maritime Dangerous Goods (IMDG~ Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. International Civil Aviation Org / International Air Transport Assoc (ICAO/IATA~ UN/ID #: Not regulated Note: Additional Federal compliance requirements may apply. See 49 CFR 171.11. LTD. QTY Passenger Aircraft Cargo Aircraft Only ~ Packaging Instruction #: I~ --- ~~ - ~~ _- ~ Max. Net Qtv. Per Packaae: -- __ ~ ~~ ~ ~ #, ,~ } ~ „ ~ ~ , t~ .A+i~~~`ag '~ x"'K ~~,`~Y.r`y ~ , ~ x r v, ~` ~'3* S'~ ~k ~c a f . ~{tt.~ . ~. Pz ~ a ~,i:~ ~: ~2 1;:;5 ~~REGULAT~ORY~IN~4RMA~;1~, ,~ r~_.x ~4~~~~ ~~~~~,~~~~~'~ ~.~~ a~ x.~~~~~.x.~~.: .~'~~~~~~~~~,~~..~~~~~ ~:~ ~~~ CERCLAlSARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds~ This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLAISARA - Section 311/312 (Titie III Hazard Cateaories Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No C~RCLA/SARA - Section 313 and 40 CFR 372• This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372: ~ Zinc Compound(s) ~ 0.4 - 1.2 ~ 1.0% ~ ~A (CERCLA) Reportable Quantity ~in pounds)• This material does not contain any chemicals,with CERCLA Reportabie Quantities. ~ f, , 722910 - 76 High Performance Full Synthetic Motor Oil (All Grades) Page 6/6 Date of Issue: 02-Apr-2007 Status: Final California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Arsenic and Inorganic Arsenic Compounds - Cancer and Developmental Toxicant Benzene - Cancer, Developmental and Reproductive Toxicant Cadmium and Cadmium Compounds -- Developmental and Reproductive Toxicant Lead and Lead Compounds - Cancer Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class None National Chemical Inventories; All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are listed on the Canadian DSL. U.S. Export Control Classification Number: EAR99 ,.. ~ ~ ~ . 1,6 ,OTHER~INFORMATI~N . ~ V~~ d `~: .r "~P ~ ~ ~ ~~~~~~ ~; -~~~~~y£~ ~~;,~ .~.'v~".. ~ .,~ .: ..,~~,~a»s„g,'~,~~ ~~$~f~r, -..a~.~'~.`'a~'~'~ - ~.'~1x,~~.~~'~~ :~.{ ~~. .^ sj~' ~.i ~, ~ ~ x <. , ~4L.,.~,w Issue Date: Status: Revised Sections or Basis for Revision: MSDS Code: 02-Apr-2007 Final Product Name / Synonyms (Section 1) 722910 MSDS Legend: ACGIH = American Conference of Govemmental Industrial Hygienists; CAS = Chemical Abstrads Service Registry; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; IARC = Intemational Agency for Research on Cancer; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada) Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are fumished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license. J ~ ,,~ ~~ ~~~~~ a 76 T5X Heavy Duty (All Grades) Material Safety Data Sheet 1':yk~PRODUCT~AND~C.OMPANY~IDENTIFIC~AT1flN~~~~~~~~'~..~_~. a. __.~~~~~~~~~~~<~...~ ' .~~.~~~~~. . ~~~. ~'~~ Product Name: 76 T5X Heavy Duty (All Grades) MSDS Code: 721860 Synonyms: 76 T5X Heavy Duty 10W 76 T5X Heavy Duty 10W-30 76 T5X Heavy Duty 15W-40 76 T5X Heavy Duty 20W-20 76 T5X Heavy Duty 30 76 T5X Heavy Duty 40 76 T5X Heavy Duty 50 Intended Use: Crankcase Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-255-9556 MSDS Information: Internet: http://w3.conocophillips.com/NetMSDS/ Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours) California Poison Control System: 800-356-3219 :~HAZ~iARDS~IDENTIFICA~TION~ r~ ~.,~~~~~~~ ~~ ~~~~`~~ ~~ ~~, ~. ~~ ~:~~a~~~~~;,,;~~~ ~ ,~~~`~~°~ , `~ ~ , x , . , r. _~5°. ~. ~~ ~s 'h';'~ r ~~ ~. .s~ .,.-`"'~.~a~ ~. ~.. . >~s :~.~.. -s,~`~i~c.;~~ ~ ~:~:3,~~'~F ;~~~u'•`~.t Emergency Overview NFPA This material is not considered hazardous according to OSHA criteria. ;0 ,. Appearance: Clear, brown Physical Form: Liquid Odor: Characteristic petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness and a burning sensation. Prolonged or repeated contact can defat the skin, causing drying and cracking of the skin, and possibly dermatitis (inflammation). No harmful effects from skin absorption are expected. Inhalation (Breathing): Expected to have a low degree of toxicity by inhalation. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders 721860 - 76 T5X Heavy Duty (All Grades) Page 1/7 Date of Issue: 23-Apr-2007 Status: Finai _~ 721860 - 76 T5X Heavy Duty (All Grades) Date of Issue: 23-Apr-2007 Page 3l7 Status: Final Methods for cleaning up: Immediate cleanup of any spill is recommended. Notify fire authorities and appropriate federal, state, and local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the National Response Center (phone number 800-424-8802). Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits (see Section 8). Do not wear contaminated clothing or shoes. Use good personal hygiene practices. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Used motor oils have been shown to cause skin cancer in mice after repeated application to the skin without washing. Brief or intermittent skin contact with used motor oil is not expected to cause harm if the oil is thoroughly removed by washing with soap and water. Storage: Keep container(s) tightly closed. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Storage temperatures above 113°F inay lead to thermal decomposition, resulting in the generation of hydrogen sulfide and other sulfur containing gases. ~ $~~~~EXPOSU.RE~CO:NTFtOLS~/~PERSONAI ~PRflTEC~`IC1N~ ~_~~~~~~' ~x~~'~~~~ ~ ~~,..:: ~ ~~~~~ ~~~~~~,, ~ _ . _ . c . __. . . . d _~ . .. ~ : ,~. ,.x,. ~~~._~ ti<,,, , ~ .s .: ~ ~ . . ~ m . ,...,., . `~~~::~~ Com o~ent~:A~ .. ~~'~,.~ ~ - ~ ~ ~~~ T ° ,, ~ ,° . -- ~~~~~ .~~.ACGIW~"~~s~~~ ~~ ~~ ~ >,,•. ~~. ~ ~,~.~a ~ :~~~~OSHA~. ;~,,~~.'~~~ ~, ..r ~ ~' A ~ ~ ~.Other .~.~.~~~~~:~;~ Lubricant Base Oil (Petroleum) TWA: 5mg/m3 TWA: 5 mg/m3 - STEL: 10 mg/m' as Oil Mist, if Generated as Oil Mist, if Generated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established exposure limits additional engineering controls may be required. Personal Protective Equipment (PPE): Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled, such as nitrile, is advised to prevent skin contact and possible irritation (see manufacturers literature for information on permeability). Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. 721860 - 76 T5X Heavy Duty (All Grades) Date of Issue: 23-Apr-2007 Page 5/7 Status: Final Reproductive: This product contains low levels of p-dodecylphenol (tetrapropenyl phenol). Rats given high, repeated daily doses of p-dodecylphenol by oral intubation experienced adverse reproductive effects. Pregnant rats given high, repeated daily doses of p-dodecylphenol by oral intubation gave birth to pups with cleft palate and skeletal malformations at dose levels that caused maternal toxicity. Follow-up studies of p-dodecylphenol in finished lubricating fluids demonstrated a no-observed effect level of 1.78 wt%. Acute Data: Lubricant oil basestocks are complex mixtures of hydrocarbons (primarily branched chain alkanes and cycloalkanes) ranging in carbon number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are found only at very low concentrations. Volatilization is not significant after release of lubricating oil basestocks to the environment due to the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process. Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities to fish, Daphnia, Ceriodaphnia and algal species are above 1000 mg/I using either water accommodated fractions or oil in water dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that acute toxicity would not be observed with these substances due to low water solubility. Resufts from chronic toxicity tests show that the no observed effect level (NOEL) usually exceeds 1000 mg/I for lubricant base oils with the overall weight of experimental evidence leading to the conclusion that lubricant base oils do not cause chronic toxiciry to fish and invertebrates. Large volumes spills of lubricant base oils into water will produce a layer of undissolved oil on the water surface that will cause direct physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments. Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch. Extensive experience from laboratory and field trials in a wide range of crops has confirmed that little or no damage is produced as a result of either aerosol exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%. ~.. 1;3'~~DISPOSAL~.CONSIDERATIONS..~ , . '~~„ ;~~.~ ~~ ~,~ ~~~~~°~ .,~z~ ~~<.~~~;~~~ ~~~ ~~~~`~,~ .~ . s, . ~~~ ~~ ~... ~. ~~_ . The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. ~ , 14 p~TF3~A`NSPORTATION,::INFQRMATiON~ ~ ~,~~~~'~ ~ ~~ ~F '`~~~~ ~' ~~~ ~~~R~~'~~~ ` {~~~~ 4~ ~ ~ ~~ - - ,~~_ ~<~.~._: . :~~.~ ~;-_ ~.~~, w E~.~~ ~ d.,~~_ ~~„~~k, ~.~~ ~ U.S. Department of Transportation (DOT~ Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) 1~2~~~ECOLO~GICA~L~INF~RIWATtON~~~~~ ~~~~~}a~~ ~~ ~~~~ ~ '~- ~~~ y ' " > ~. _._. . , _ . _.~~... .... ,., .~a,..,.,~~~ °~>~.~~~:~,~ ~a ~~~~. ,~x.~~., ~ . ,. ~,~,. ,. ~ . _ r .~.. . _ N>~x~~~._ ~x _~ 721860 - 76 T5X Heavy Duty (All Grades) Date of Issue: 23-Apr-2007 .~ Page 6/7 Status: Final ... ,~ .._ r x . . ,~ ... ,r : ~' 3 a ~. ~. ~v~ ~ s ~s ~ h s.x~~^+~ a ~ 1~4 ~.~TRANSPt~R~TATiQN~INFOR ~ ~I~N~~~ .. ~~~4 ~~ x' '~ E~ _ ~~ ; t zx~~~~~ ~~ ~~ ~~ .. ~~,~~~~~~ ~ ;~~ x ~_ti > ~ ~.- .~~,. ~~ ~y ~ laternational Maritime Dangerous Goods (IMDG~ Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. International Civil Aviation Org. I International Air Transport Assoc. (ICAO/IATA~ UN/ID #: Not regulated Note: Additional Federal compliance requirements may apply. See 49 CFR 171.11. LTD. QTY Passenger Aircraft Cargo Aircraft Only ~ Packaginq Instruction #: II -- II --- II -- I I Max. Net Qtv. Per Packaae: II - II __ __ .. n~G ~ °~ ~ ~ :°? ~ ~ f ~ x ~ ,: ~~.5~~REGU ~..::T~+URY~iNF~JRMATIC?~IX`~.,,~~~~~.~k; ~. ~~ ~.~~ ~~u~~ _ _ .~ ~~ .~: ~ ~~~~ :k~~ .', ~.~ ~~ ~~~~ ~g~ .,~~ ~~~~~~ .: CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds~ This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III Hazard Cateaories Acute Health: No Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No CERCLA/SARA - Section 313 and 40 CFR 372• This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372: "~ ~' "~y~. v ~ ;' ~mha ~ ~- ~ ~ u~s ~ ~ ~ ~ . . . ,a~ r . . ~ ~', ' ~,~~:. ~,'„z~fi~ ~~~~,~~4 , ~'i0I#IpOll@~~~ ~~;~~~~t~as~~s-;,~~'~*~;~'~§ ~..v_ ~r0[IC@Il ~~lO~„#W~~~~'`~~'k~,~ i~ Pc~d,.~ ~e`,1~~~~,I~IS,~'e``'-~ ~ .> ' Zinc Compound(s) 0.5 - 2.0 ~,p~/a ~PA (CERCLA) Reportable Quantipr (in pounds)• This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): ~~~.,~ ,~'~ ~~, ~ x~~ ~ Cotii'~onent~~,°~ `~ ~ ~ ~:~ ~F: , ~~~;~~..~~_, .~.~,s,:' ~~~ .~~~ ~~~ , ~~ ~~ ~ ~ ~. ~ ~ ~ ~,~..~~ ~, ~ ~.~. ~ ,;~,~T ;of Tazi+ci ~~~~~~ ~• ~ „~~~~~ ~ Benzene Cancer Developmental Toxicant Male Re roductive Toxicant Lead / Lead Compounds Cancer Developmental Toxicant Female Reproductive Toxicant Male Re roductive Toxicant Arsenic Inor anic Arsenic Com ounds Cancer Cadmium / Cadmium Compounds Cancer Developmental Toxicant Male Re roductive Toxicant Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. ~ ~~ ~~i~~'1 ~s~~~ ~ IV~P Gear Lube Material Safety Data Sheet 1~~PRQDUCT,AND~;.COMPANY~~IDENT1~1C1~1TION~~~~"''~~, ,~5. `:;.~~~~,;~ ~~` ~ ~~ ~ ~~~~~~~~~~~~~~~~ Product Name: MP Gear Lube MSDS Code: 720260 Synonyms: 76 MP Gear Lube, SAE 75W-90 76 MP Gear Lube, SAE 80W-90 76 MP Gear Lube, SAE 85W-140 76 MP Gear Lube, SAE 90 76 MP Gear Lube, SAE 140 Intended Use: Automotive Gear Oil Responsible Party: ConocoPhillips Lubricants 600 N. Dairy Ashford Houston, Texas 77079-1175 Customer Service: 888-766-7676 Technical Information: 800-255-9556 MSDS Information: Internet: http://w3.conocophillips.com/NetMSDS/ Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours) Califomia Poison Control System: 800-356-3219 . ° ~ H~A~7:ARDS IDENTIFICATIO~N ~~ ~ ~~ "~ ~ ~~ ''~ ~~~~ ~ ~ ~ ~~~~ , °~ ~~~~~> ~~~-~ ~ ~ ~ ~ ~~~ ~ ~ ~ ... ~ _. ._.. _.._ _.,_ , :..., _~t .~ ~ ~.......e.~~s~~.s-~3~~ '~x.r~z .~a..~'~. ,... ~..:~M'~~~:~`~~ s+F'~~~.~~~>x~t~~~~,~~5r."~'"~.a~,. '~' $~~'a~.'~°a.'~. ~t~.,a~".~'~~ Emergency Overview NFPA This material is not considered hazardous according to OSHA criteria. i ~'.~ Appearance: Clear amber Physical Form: Liquid Odor: Petroleum Potential Health Effects Eye: Contact may cause mild eye irritation including stinging, watering, and redness. Skin: Contact may cause mild skin irritation including redness and a buming sensation. Prolonged or repeated contact can defat the skin, causing drying and cracking of the skin, and possibly dermatitis (inflammation). A component of this material may cause an allergic skin reaction. No information available on skin absorption. Inhalation (Breathing): No information available on acute toxicity. Ingestion (Swallowing): No harmful effects expected from ingestion. Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract, nausea and diarrhea. Inhalation of oil mist or vapors at elevated temperatures may cause respiratory irritation. Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders. See Section 11 for additional Toxicity Information. 720260 - MP Gear Lube Page 1/7 Date of Issue: 30-Aug-2007 Status: Final 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 217 Status: Final .. ~ ~ ~ 3'~COMPO'S'ITION;~/~~NFO,RMATION :ON IN,GRELI1ENTk5a4~.~~~~,,_:,,~~~s~.~~~~'`~°~~~ ~k;~~~~~:~~ ~ ~~~~~.~~s„~~~~~'~ Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a waterless hand cleaner. If irritation or redness develops and persists, seek medical attention. Inhalation (Breathing~: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention. Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention. Notes to Physician: Acute aspirations of large amounts of mineral oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. ~ ~r; ~~ ~ ~ . ~u .t~FIRE'FIGHTING~MEA`~SURES~~~~~~~~~~ ~~~~~ ' ~~~`'~ ~'~~~~~~~~ ~~ k ~~ ~~x~ ~,~~. ~~¢: .:~ _.. . ... , ~ ,., a: . f,~,~'. 's»~:?~ , ,.~, i~ ~Ihi ..a. ~4 ~~.~.d~'~b."u~....k''~,.~ , «. S,.a~. f ^r ~. '~ s~S~~~'~~. ,s~. c ~~ ~u; .~ $~ NFPA 704 Hazard Class Health: 0 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe) Unusual Fire 8~ Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of materials heated above 212°F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8). Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move undamaged containers from immediate hazard area if it can be done with minimal risk. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes. See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits r, . _ _ ~ _ .. ~ _ ~ ~ ~: ~, a } ~ ~ s ~ ~ .~ ~ ~ ~ ~~ ~ ~ ~ 6~ ACCIDENTAL RELEASE INIEASURES~ ~ 4 ax~ ~ ~~~ ~ z ~ ~~ ~ ~~,Y~ ~~~~ ~ ~~r ~~ ~ ~`~~~ s~~& ~` ~ _~. ...._ .-. ~ , ~ ~ ~s ~ ~' , .~ ' ~~~~s ~ ~~~ r.~~s~, ~~ ~~~~~ ~ ~3~ ~'~ ~ ~~ ~'~ ~ ` a~.. _m ~; • Personal Precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release. The use of explosion-proof electrical equipment is recommended. Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8). See Sections 2 and 7 for additional information on hazards and precautionary measures. Environmentai Precautions: Stop spill/release if it can be done with minimal risk. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number 800-424-8802). ,-~ .~ .. ~ ~ 3° ,~, x ..~ ~ ~ ~~ ~: ~FIRST~-AI ~ MEA~SURES~ ~~~°.~' .:.~,~~~ ~ ~~ ~~~~~~~~~~~~ ~~~~~~~ '~~~~; ~ ~ ~ ~ ~~~~,~'~~~~~~~-~~~ H..~ ,~ ~ , o ~~ . . _ ,~ r , ~ ~ ~ ~ _ ,&~. ,_~ ~» ..~.~nm F.a ~~a~~ ~ ~~~~~ .~,<s,. ~.. : ~a.. ~~~a~.~,<~ n~~~.;~~; 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 3/7 Status: Final Methods for Containment and Clean-Up: Notify fire authorities and appropriate federal, state, and local agencies. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposai. Spilled material may be absorbed into an appropriate absorbent material. .., i ~~~HAtVDLIPIG,`AND~STORAiGE~~~~~~ ~~~~`~~ ~;~ ~,~, ~ ~ ~.~~~ ~~~,`~~~~~~,~~~~~'~~:4' K~~~~~~ ~~s~: _ . ~ _ . , ..~ ,~ . ~.. ~"~..~,,~ , t~~.N. ~a~,,'~~., .~~~~ y~ .~. ~k~.~.rm~'a; .~ ~ '~"~ ~`c " ~ ~~1..~~~~.~tT. . ~«~:~~ a~ ~.~~ . ~~~~ Precautions for safe handling: Wash thoroughly after handling. Use good personal hygiene practices and wear appropriate personal protective equipment. Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and 29CFR 1910.146. Do not wear contaminated clothing or shoes. "Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be completely.drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed of in an environmentally safe manner and in accordance with govemmental regulations. Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other references pertaining to cleaning, repairing, welding, or other contemplated operations. Conditions for safe storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect container(s) against physical damage. , ~~EXPOSURE~CONTR~LS~/~PERSONAI~~PROTECTlOi~x :~ "~ ~` ~~~°~ ~ s~~~~~s ' ~~~' ~ c' ~~;"~~p~ .a _ ~, . ,d4,s"tt`~.,~.., ,.:~_ ,a.ak`.x.a ~P-A.,~sx .~t b. . , v~.. ;c ~~`. ~; ~!Com °~onent~"~~~~:~~ ~~~°~ ~~AGGiH $ ~,~ ~~. ~ ~ ~~:~"~.~~ ~ ~O ~,~.~~~~<. r 5HA'Y a~~~~~`;~~ ; '~~ :'~~~'~~~~Othe ,r. ~.~~~~'~.A :~~~ Lubricant Base Oil (Petroleum) TWA: 5mg/m3 TWA: 5 mg/m3 - STEL: 10 mg/m' as Oil Mist, if generated as Oil Mist, if enerated Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information. Engineering controls: If current ventilation practices are not adequate to maintain airbome concentrations below the established exposure limits, additional engineering controls may be required. ~ Personal Protective Equipment (PPE): Eye/Face: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Depending on conditions of use, a face shield may be necessary. Skin: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers tc confirm the performance of their products. Suggested protective materials: Nitrile Respiratory: Where there is potential for airbome exposure above the exposure limit a NIOSH certified air purifying respirator equipped with R or P95 filters may be used. A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed whenever workplace conditions warrant a respirator's use. Air purifying respirators provide limited protection and cannot be used in atmospheres that exceed the maximum use concentration (MUC) as directed by regulation or the manufacturer's instructions, in oxygen deficient (less than 19.5 percent oxygen) situations, or other conditions that are immediately dangerous to life and health (IDLH). Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the perFormance of their protective equipment. Specifc situations may require consultation with industrial hygiene, safety, or engineering professionals. . „ .. .. V _ m , 9:~~PHY;SICAL`~AND CHEMIC°AL PROPERTIES~=~~ ~~" '~~~~',~, ~`~ ~` ~, ~;: ~~ „~,,~,~,~~ : ~~~~~~ ~~ :~~~~~x~ y~, ~~ ~'~~~ ~~ _ _..~ _ _. . _ . .. ~ ~... ~,_ ~.~.._ ~ ~ ~ ,~<< Note: Unless otherwise stated, values are determined at 20°C (68°F) and 760 mm Hg (1 atm). Data represent typical values and are not intended to be specifications. Appearance: Clear amber Physical FoRn: Liquid Odor: Petroleum 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 4/7 Status: Finat Odor Threshold: pH: Vapor Pressure: Vapor Density (air-1): Boiling Point/Range: Melting/Freezing Point: Solubflity in Water: Partition Coefficient (n-octanol/water) (Kow) Specific Gravity: Bulk Density: Viscosity: Percent Volatile: Evaporation Rate (nBuAc=1): Flash Point: Test Method: LEL (vol % in air): UEL (vol % in air): Autoignition Temperature: No data Not applicable <1 >1 No data No data Negligible No data 0.87 - 0.91 @ 60°F (15.6°C) 7.24 - 7.58 Ibs/gal 14.0 - 32.0 cSt @ 100°C; 97 - 441 cSt @ 40°C Negligible <1 Minimum 302°F / 150°C Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010 No data No data No data ~ ; , ~ 10'~ ST~ 'BILIT~Y XAND ~ ~£~ ~ '~~~ ~~ `~ ~ } , ~~ . .A < ~ ~~ ~._ ~ ~REACTIUI~'TY~,.~ ~ ~ . ~v~~~~ .~ .~ ~ . .~ ~ ~~~, .. °~ ~ ~;~'.~~'~~~~~'~~ ~ „~~~.~ . ~ µ~'~~ . , ~ Stability: Stable under normal ambient and anticipated conditions of storage and handling. Conditions to Avoid: Extended exposure to high temperatures can cause decomposition. Materials to Avoid (Incompatible Materials): Avoid contact with oxidizing agents and reducing agents. Hazardous Decomposition Products: Combustion can yield oxides of carbon, nitrogen, sulfur and phosphorus. : -. ..: .. .. ,. r .. ~ . K v'~ rr2 "tt~;,'~~ z~ b'* v ~~ ~~ _~ _ . r ~~ ~ 1~1~t TOXICOLOGIC~AL~INF4RMA~TION >~,~~ ~~.~~,~~~~~~.~~~~x;~ _ ~~°' ~~~~~~~~ .~~. ~~~~~~~.~~~~~~~~.~~~~ Chronic Data: Lubricant Base Oil (Petroleum) Caricinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes including solvent extraction, hydrotreating, and/or dewaxing to remove aromatics and improve perFormance characteristics. They contain low concentrations of PAH's and none have been identified as a carcinogen by NTP, IARC or OSHA. Acute Data: '1=2~~ECOLOGICAL~~INFQRMATIONi~~= ~~~~~~~~` ~~~~:~~'~~-~,~~~~~ ~~°,~ ~~~~ ~~ : ~~~ ~;~~ ~~:~~~;~ ~~ ~ ~~" ~~~:~~; 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 5/7 Status: Final 1'"~2' ~ECOLOGICA~~~iNFQRMAT~t3M~~ `: ~R ~~ ~ , ~ ~`` `` ~ ~fr ~ ' z c._ , , _. . . . . . . c~. . ~ ~5a ~~~'..~.~~- ~~,:~~~ ~~~~~ ~~~~~~~~ `"~~~ ~` ~ ~ ~~~~ ~3~ ~~ ,.P~ ,. ~z, ,i~«r ~ ~:.. Lubricant oil basestocks are complex mixtures of hydrocarbons (primarily branched chain alkanes and cycloalkanes) ranging%in carbon number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are found only at very low concentrations. Volatilization is not significant after release of lubricating oil basestocks to the environment due to the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process. Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities to fish, Daphnia, Ceriodaphnia and algal species are above 1000 mg/I using either water accommodated fractions or oil in water dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that acute toxicity would not be observed with these substances due to low water solubility. Results from chronic toxicity tests show that the no observed effect level (NOEL) usually exceeds 1000 mg/I for lubricant base oils with the overall weight of experimental evidence leading to the conclusion that lubricant base oils do not.cause chronic toxicity to fish and invertebrates. Large volumes spills of lubricant base oils into water will produce a layer of undissolved oil on the water surface that will cause direct physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments. Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch. • Extensive experience from laboratory and field trials in a wide range of crops has confirmed that little or no damage is produced as a result of either aerosol exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%. .. .,. ... ._ f ~r I'~ ~ ~'~° 1 s~~ ? S-~ 4xa?>2; i ~ c ~ ~ , 1;3~, DISPl7SAL G.ON5,1D;~RA`TIaI~S~~ _ ~ ~ ~ ' ~` ~ x ~ ~ ~ ~ ~ * ~~E y A ~ ~° '`~~` ~ ~ ~~~, ~ ~~~ - i _ ~ ~ ~.~ a~ . ~~~~ ~~ .~ H .~ ~~~x~c~~~. ~~v. ~-~~ ~3 ,r. ~ •~~ a~.. _ uz~ . t ~"~~ _~ ~ `~o~, ~ ~_ ~-~~~ _ ~ ~ The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and local requirements in addition to federal regulations. This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9 for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this material could subject it to regulation as a hazardous waste. This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be completely used and containers should be emptied prior to discard. 1;4 ~,TRANSPORTATII~~NxINF.O.RMATIC)N~~,~~ ~~ :~~.~~~~. _ `;~~~ ,~:~_~~~~~;~~~;fix.,~~~~ ~~~~~~~ ~ ..~~~~~ ~`~~~ . ~,~~ U.S. Department of Transportation (DOT~ Shipping Description: Not regulated Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of 49 CFR, Part 130 apply. (Contains oil) International Maritime Dangerous Goods (IMDGl Shipping Description: Not regulated Note: Federal compliance requirements may apply. See 49 CFR 171.12. International Civil Aviation Org / International Air Transport Assoc (ICAO/IATAI UN/ID #: Not regulated LTD. QTY Passenger Aircraft Cargo Aircraft Only Packa in Instruction #: --- ___ ___ Max. Net Q. Per Packa e: --- --- ___ 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 6/7 Status: Final 15>°~r:REGULiATORY~IN~~RMA<.~IDN=~~~4~~r:.an~`~,~~~...~~~~~~ .~~~~E ~~~°~~~~~ ~.~~~..~r~~„~~' ~~ ~~'~~~~~y,~~`~~~~ CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds~ This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372. CERCLA/SARA - Section 311/312 (Title III_Hazard Cateaories Acute Health: No . Chronic Health: No Fire Hazard: No Pressure Hazard: No Reactive Hazard: No ~RCLA/SARA - Section 313 and 40 CFR 372• This materral does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372. EPA (CERCLA) Reportable Quantitv (in pound )• This material does not contain any chemicals with CERCLA Reportable Quantities. California Proposition 65: Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65 (CA Health 8 Safety Code Section 25249.5): . ..TMd . ^ ~~ :r ~ <t _ _ - ,~ , ~.~~ :. ,.s,~~ ~~` .~.~ .~-; .,e , _w u~~Com onent';~:~~.~~~~~;; `~ z.~~~~~~._ x •~ ~ r, , . -~ ~".;~.~~ ~~~~ _ ~ ~~T"~~of~Toxici ~~ ~~~~~ ~~~~~ ~ _ . ~` _. . . ~.~ , ~~~, : _~ . ,. Eth I Ac late Cancer Lead / Lead Compounds Cancer Developmental Toxicant Female Reproductive Toxicant Male Re roductive Toxicant Arsenic Inor anic Arsenic Com ounds Cancer Cadmium / Cadmium Compounds Cancer Developmental Toxicant Male Re roductive Toxicant Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class None Nationai Chemical Inventories: All components are either listed on the US TSCA Inventory, or are not regulated under TSCA. All components are listed on the Canadian DSL. U.S. Export Control Classification Number: EAR99 , ~ y" " 'N z *~? ~, w~" 3'~8 s c r~ 4 x ~?u e ~'^ x.X~ £ d Ya Yk l~~c y; 1;6~ ~OTHER~INFORMATI`ON ~~~~ 5 s ~=~~' °~~.,, g~~,~.l,~, ~ ~~ ~ ~ ~ ~ ~~ ~~ ~ k ~~~~ k ~ , ~ ~~ ~~ ~ ,:~ . ~ . .. . , , f.~~ ~~ ,s ~ ~...a _~..,,. R..: ., k,.kL:r,°. ,.. ~,A. .. ~.:? a.'a. . ~Y~',.°'~5.... Y;F Z~"Yw'i{~tl~ . ~..Yad~~~~ hx~'.ff~.~z. . L~~Ri ?aFYk~,~.". ~.. ~ u.'~eC~~»'~~'.s.1 ~ ~. . ~ S, }: ~..4~~.~~ar~w?~~ Issue Date: 30-Aug-2007 Status: Final Revised Sections or Basis for Revision: Periodic review and update MSDS Code: 720260 MSDS Legend: ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service Registry; CEILING = Ceiling Limit (15 minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; IARC = Intemational Agency for Research on Cancer; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Tiine Weighted Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materiais Information System (Canada) ~1 ~ 720260 - MP Gear Lube Date of Issue: 30-Aug-2007 Page 7l7 Status: Finai Disclaimer of Expressed and implied Warranties: The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are fumished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any patented invention without a license.